Publications
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2023. U-C Bond Insertion, Ring-Opening, and C-H Activation in a Uranium Bis(diisopropylamino)cyclopropenylidene (BAC) Adduct. Organometallics. 42:1005–1012.
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2015. Thorium-ligand multiple bonds via reductive deprotection of a trityl group. Chem Sci. 6:3891-3899.
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2013. Tetrahalide complexes of the [U(NR)2]2+ ion: synthesis, theory, and chlorine K-edge X-ray absorption spectroscopy. J Am Chem Soc. 135(6):2279-90.
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2021. Synthesis of Parent Acetylide and Dicarbide Complexes of Thorium and Uranium and an Examination of Their Electronic Structures. Inorganic Chemistry. 60:15413–15420.
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2020. Synthesis of a “Masked” Terminal Zinc Sulfide and its Reactivity with Brønsted and Lewis Acids. Angew. Chem. Int. Ed.. 59:8947-8951.
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2012. Synthesis, molecular and electronic structure of UV(O)[N(SiMe3)2]3. Inorg Chem. 51(3):1625-33.
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2013. Synthesis and spectroscopic and computational characterization of the chalcogenido-substituted analogues of the uranyl ion, [OUE]2+ (E = S, Se). J Am Chem Soc. 135(14):5352-5.
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2021. Synthesis and Electronic Structure Analysis of the Actinide Allenylidenes, [(NR2)3An(CCCPh2)]- (An = U, Th; R = SiMe3). Chemical Science. 12:14383-14388.
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2019. Synthesis and Crystallographic Characterization of the Tetravalent Actinide-DOTA Complexes [AnIV(κ8-DOTA)(DMSO)] (An = Th, U). Inorganic Chemistry. 58:8253-8256.
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2021. Synthesis and Characterization of Two “Tied-Back” Lithium Ketimides and Isolation of a Ketimide-Bridged [Cr2]6+ Dimer with Strong Antiferromagnetic Coupling. Inorganic Chemistry. 60:4996–5004.
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2022. Ring-opening of a Thorium Cyclopropenyl Complex Generates a Transient Thorium-bound Carbene. Chem. Commun.. 58:6805-6808.
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2023. Ring-Opening in the Actinide Cyclopropyl Complexes [Cp3U(2,2-Diphenylcyclopropyl)]n− (n = 0, 1). Organometallics. 42:2347–2352.
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2014. Reductive silylation of a uranyl dibenzoylmethanate complex: an example of controlled uranyl oxo ligand cleavage. Chem Sci. 5:3204-3213.
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2021. Reductive Coupling of Xylyl Isocyanide Mediated by Low-Valent Uranium. Organometallics. 40:2934–2938.
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2020. Redox-switchable carboranes for uranium capture and release. Nature. 577:652–655.
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2020. Redox-switchable carboranes for uranium capture and release. Nature. 577:652–655.
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2020. Reactivity of [Ce(NR2)3] (R = SiMe3) with Prospective Carbon Atom Transfer Reagents. Organometallics. 39:2375–2382.
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2013. A rare uranyl(VI)-alkyl ate complex [Li(DME)1.5]2[UO2(CH2SiMe3)4] and its comparison with a homoleptic uranium(VI)-hexaalkyl. Angew Chem Int Ed Engl. 52(11):3259-63.
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2011. Probing the reactivity and electronic structure of a uranium(V) terminal oxo complex. J Am Chem Soc. 133(36):14224-7.
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2020. Probing the Electronic Structure of a Thorium Nitride Complex by Solid-State 15N NMR Spectroscopy. Inorganic Chemistry. 59:10138–10145.
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2022. Photolytic or Oxidative Fragmentation of Trityl Diazeniumdiolate (O2N2CPh3–): Evidence for Both C–N and N–N Bond Cleavage. Inorganic Chemistry. 61:14924–14928.
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2018. Organometallic Actinide Complexes with Novel Oxidation States and Ligand Types. Experimental and Theoretical Approaches to Actinide Chemistry. :181–236.
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2023. NO and N2O Release from the Trityl Diazeniumdiolate Complexes [M(O2N2CPh3)3]− (M = Fe, Co). Inorganic Chemistry. 62:4847–4852.
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2022. Metal–Metal-Bonded Fe4 Clusters with Slow Magnetic Relaxation. Inorganic Chemistry. 61:9997–10005.
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2016. Formation of a Ce(IV) Oxo Complex via Inner Sphere Nitrate Reduction. Journal of the American Chemical Society. 138:12743-12746.
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2013. Enediolate–Dilithium Amide Mixed Aggregates in the Enantioselective Alkylation of Arylacetic Acids: Structural Studies and a Stereochemical Model. J Am Chem Soc. 135:16853-16864.
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2019. Enantioselective Alkylation of 2-Alkyl Pyridines Controlled by Organolithium Aggregation. Journal of the American Chemical Society. 141:15024-15028.
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2023. Dimerization and ring-opening in bis(diisopropylamino)cyclopropenylidene (BAC) mediated by [U(NR2)3(CCPh)] (R = SiMe3). Dalton Transactions. Advance Article
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2020. Coordination of Uranyl to the Redox-Active Calix[4]pyrrole Ligand. Inorganic Chemistry. 59:8629–8634.