Publications
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2022. Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes. Chem. Sci.. 13:3369-3374.
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2022. Structural and Spectroscopic Characterization of a Zinc-Bound N-Oxyphthalimide Radical. Inorganic Chemistry. 61:13250–13255.
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2021. Synthesis and Characterization of Two “Tied-Back” Lithium Ketimides and Isolation of a Ketimide-Bridged [Cr2]6+ Dimer with Strong Antiferromagnetic Coupling. Inorganic Chemistry. 60:4996–5004.
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2021. Synthesis and Characterization of Two Uranyl-Aryl “Ate” Complexes. Chemistry – A European Journal. 27:5885-5889.
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2021. Synthesis and Electronic Structure Analysis of the Actinide Allenylidenes, [(NR2)3An(CCCPh2)]- (An = U, Th; R = SiMe3). Chemical Science. 12:14383-14388.
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2021. Synthesis of a Mixed-valent Heterobimetallic Actinide Nitride and an Analysis of its Bonding. Chemical Science. 12:15519-15527.
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2021. Synthesis of Bis(trityl)iron(II) and Formation of the Iron(0)-Stabilized o,o-Isomer of Gomberg’s Dimer. Organometallics. 40:4045–4049.
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2021. Synthesis of Parent Acetylide and Dicarbide Complexes of Thorium and Uranium and an Examination of Their Electronic Structures. Inorganic Chemistry. 60:15413–15420.
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2020. Synthesis of a “Masked” Terminal Zinc Sulfide and its Reactivity with Brønsted and Lewis Acids. Angew. Chem. Int. Ed.. 59:8947-8951.
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2019. Synthesis and Characterization of a Linear, Two-Coordinate Pt(II) Ketimide Complex. Inorganic Chemistry. 58:15927-15935.
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2019. Synthesis and Characterization of “Atlas-Sphere” Copper Nanoclusters: New Insights into the Reaction of Cu2+ with Thiols. Inorganic Chemistry. 58:8739-8749.
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2019. Synthesis and Crystallographic Characterization of the Tetravalent Actinide-DOTA Complexes [AnIV(κ8-DOTA)(DMSO)] (An = Th, U). Inorganic Chemistry. 58:8253-8256.
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2019. Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li]2[M(N═CtBuPh)6] (M = Ce, Th). Inorganic Chemistry. 58:12654-12661.
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2018. Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N2O reduction. Chem. Sci.. 9(31):6580-6588.
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2017. Subnanometer-Sized Copper Clusters: A Critical Re-evaluation of the Synthesis and Characterization of Cu8(MPP)4 (HMPP = 2-Mercapto-5-n-propylpyrimidine). Inorganic Chemistry. 56:8390–8396.
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2017. Synthesis of a terminal Ce(iv) oxo complex by photolysis of a Ce(iii) nitrate complex. Chem. Sci.. 8:7873-7878.
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2017. Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium. Organometallics. 36:4519–4524.
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2016. Synthesis and Reactivity of a U(IV) Dibenzyne Complex. Organometallics. 35:494-502.
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2016. Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)4(OAc)2] and [Cu3H(dppm)3(OAc)2]. Inorg. Chem.. 55:12435-12440.
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2016. Synthesis, Electrochemistry, and Reactivity of the Actinide Trisulfides [K(18-crown-6)][An(η3-S3)(NR2)3] (An = U, Th; R = SiMe3). Inorganic Chemistry. 55:9150-9153.
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2016. Synthesis, structure and bonding of hexaphenyl thorium(iv): observation of a non-octahedral structure. Chem Commun (Camb). 52(4):689-92.
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2015. Synthesis and characterization of a Cu14 hydride cluster supported by neutral donor ligands. Chem Eur J. 21(14):5341-4.
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2015. Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide. Angew Chem Int Ed Engl. 54(49):14956-9.
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2014. Synthesis of terminal monochalcogenide and dichalcogenide complexes of uranium using polychalcogenides, [En]2- (E = Te, n = 2; E = Se, n = 4), as chalcogen atom transfer reagents. Inorg Chem. 53(19):10240-7.
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2014. Synthesis of uranium-ligand multiple bonds by cleavage of a trityl protecting group. J Am Chem Soc. 136(1):96-9.
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2013. Synthesis and spectroscopic and computational characterization of the chalcogenido-substituted analogues of the uranyl ion, [OUE]2+ (E = S, Se). J Am Chem Soc. 135(14):5352-5.
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2013. Synthesis of a cobalt(IV) ketimide with a squashed tetrahedral geometry. Chem Commun (Camb). 49(28):2888-90.
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2012. Synthesis and characterization of [M2(N=CtBu2)5]- (M=Mn, Fe, Co): metal ketimide complexes with strong metal-metal interactions. Angew Chem Int Ed Engl. 51(51):12772-5.
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2012. Synthesis and reactivity of a uranyl-imidazolyl complex. Chem Commun (Camb). 48(10):1484-6.
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2012. Synthesis, molecular and electronic structure of UV(O)[N(SiMe3)2]3. Inorg Chem. 51(3):1625-33.
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2011. Silylation of the uranyl ion using B(C6F5)3-activated Et3SiH. Inorg Chem. 50(19):9642-9.
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2011. Stabilizing high-valent metal ions with a ketimide ligand set: synthesis of Mn(N=CtBu2)4. Inorg Chem. 50(10):4660-8.
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2011. Synthesis of a phosphorano-stabilized U(IV)-carbene via one-electron oxidation of a U(III)-ylide adduct. J Am Chem Soc. 133(18):6894-7.
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2010. Structural characterization of a copper nitrosyl complex with a {CuNO}10 configuration. J Am Chem Soc. 132(41):14336-7.
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2010. Synthesis and characterization of an iron(IV) ketimide complex. J Am Chem Soc. 132(37):12814-6.
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2010. Synthesis of a nitrido-substituted analogue of the uranyl ion, [N=U=O]+. J Am Chem Soc. 132(20):6888-9.
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2009. Synthesis and redox chemistry of high-valent uranium aryloxides. Inorg Chem. 48(7):3000-11.
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2008. Synthesis and characterization of three homoleptic alkoxides of uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UVtBu)6], and UVI(OtBu)6. Inorg Chem. 47(11):4752-61.
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2008. Synthesis and reactivity of bis(imido) uranium(VI) cyclopentadienyl complexes. Chem Commun (Camb). (40):4986-8.
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2008. Synthesis, characterization, and reactivity of a uranyl β-diketiminate complex. J Am Chem Soc. 130(6):2005-14.
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2006. Synthesis and reactivity of the imido analogues of the uranyl ion. J Am Chem Soc. 128(32):10549-59.
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2005. Synthesis of imido analogs of the uranyl ion. Science. 310(5756):1941-3.
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2004. The solid-state molecular structure of W(NO)3Cl3 and the nature of its W-NO bonding. Can J Chem. 82:285-292.
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2002. Synthesis, characterization, and solution redox properties of (trimpsi)M(CO)2(NO) complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3]. Inorg Chem. 41(16):4114-26.