Publications

Found results
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Vincenzini BD, Yu X, Paloc S, Smith PW, Gupta H, Pandey P, Kent GT, Ordoñez O, Keller T, Gau MR et al..  2025.  4f-orbital covalency enables a single-crystal-to-single-crystal ring-opening isomerization in a Ce-cyclopropenyl complex.. Nat Chem. in press
A
Ordoñez O, Yu X, Schuerlein MA, Wu G, Autschbach J, Hayton TW.  2024.  An Actinide Complex with a Nucleophilic Allenylidene Ligand. Journal of the American Chemical Society. 146:28306–28319.
Ordoñez O, Yu X, Wu G, Autschbach J, Hayton TW.  2022.  Assessing the 4f Orbital Participation in the Ln–C Bonds of [Li(THF)4][Ln(C6Cl5)4] (Ln = La, Ce). Inorganic Chemistry. 61:15138–15143.
C
Hayton TW, Boncella JM, Scott BL, Abboud KA, Mills RC.  2005.  Coupling of an aldehyde or ketone to pyridine mediated by a tungsten imido complex. Inorg Chem. 44(25):9506-17.
Nguyen TH, Ausman SF, MacGregor F, Wu G, Fortier S, Hayton TW.  2025.  The Curious Case of [AnH(NR2)3] (An = Th, U; R = SiMe3): Two Monomeric Actinide Hydrides Revisited. Organometallics. 44:105–114.
E
Hertler PR, Yu X, Brower JD, Nguyen T-AD, Wu G, Autschbach J, Hayton TW.  2024.  Exploring Spin-Orbit Effects in a [Cu6Tl]+ Nanocluster Featuring an Uncommon Tl-H Interaction. Chemistry – A European Journal. 30:e202400390.
H
Ordoñez O, Yu X, Wu G, Autschbach J, Hayton TW.  2021.  Homoleptic Perchlorophenyl "Ate" Complexes of Thorium(IV) and Uranium(IV). Inorganic Chemistry. 60:12436–12444.
L
Yu K, Lu P, Jackson JJ, Nguyen T-AD, Alvarado J, Stivala CE, Ma Y, Mack KA, Hayton TW, Collum DB et al..  2017.  Lithium Enolates in the Enantioselective Construction of Tetrasubstituted Carbon Centers with Chiral Lithium Amides as Noncovalent Stereodirecting Auxiliaries. Journal of the American Chemical Society. 139:527-533.
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Assefa MK, Pedrick EA, Wakefield ME, Wu G, Hayton TW.  2018.  Oxidation of the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene upon Ligation to the Uranyl Ion. Inorganic Chemistry. 57(14):8317–8324.
P
Sergentu D-C, Kent GT, Staun SL, Yu X, Cho H, Autschbach J, Hayton TW.  2020.  Probing the Electronic Structure of a Thorium Nitride Complex by Solid-State 15N NMR Spectroscopy. Inorganic Chemistry. 59:10138–10145.
Q
Ordoñez O, Yu X, Wu G, Autschbach J, Hayton TW.  2024.  Quantifying Actinide–Carbon Bond Covalency in a Uranyl–Aryl Complex Utilizing Solution 13C NMR Spectroscopy. Inorganic Chemistry. 63:9427–9433.
R
Kent G, Yu X, Wu G, Autschbach J, Hayton TW.  2022.  Ring-opening of a Thorium Cyclopropenyl Complex Generates a Transient Thorium-bound Carbene. Chem. Commun.. 58:6805-6808.
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Ordoñez O, Yu X, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis and Characterization of Two Uranyl-Aryl “Ate” Complexes. Chemistry – A European Journal. 27:5885-5889.
Kent G, Yu X, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis and Electronic Structure Analysis of the Actinide Allenylidenes, [(NR2)3An(CCCPh2)]- (An = U, Th; R = SiMe3). Chemical Science. 12:14383-14388.
Assefa MK, Sergentu D-C, Seaman LA, Wu G, Autschbach J, Hayton TW.  2019.  Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li]2[M(N═CtBuPh)6] (M = Ce, Th). Inorganic Chemistry. 58:12654-12661.
Assefa MK, Sergentu D-C, Seaman LA, Wu G, Autschbach J, Hayton TW.  2019.  Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li]2[M(N═CtBuPh)6] (M = Ce, Th). Inorganic Chemistry. 58:12654-12661.
Assefa MK, Wu G, Hayton TW.  2017.  Synthesis of a terminal Ce(iv) oxo complex by photolysis of a Ce(iii) nitrate complex. Chem. Sci.. 8:7873-7878.
Kent GT, Yu X, Pauly C, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis of Parent Acetylide and Dicarbide Complexes of Thorium and Uranium and an Examination of Their Electronic Structures. Inorganic Chemistry. 60:15413–15420.
Erlemeier L, Hertler PR, Wu G, Xie X, Autschbach J, Schenberg LA, Ducati LC, Hayton T, von Hänisch C.  2025.  Synthesis, Structure, and 199Hg Chemical Shifts of Mercury 1,5,9-trimesityldipyrromethene (MesDPM) Complexes. Chemistry – A European Journal. Accepted Article:e202501460.
T
Ng SHK, Adams CS, Hayton TW, Legzdins P, Patrick BO.  2003.  Thermal activation of hydrocarbon C-H bonds initiated by a tungsten allyl complex. J Am Chem Soc. 125(49):15210-23.
U
Nguyen TH, Yu X, Kent GT, Autschbach J, Hayton TW.  2023.  U-C Bond Insertion, Ring-Opening, and C-H Activation in a Uranium Bis(diisopropylamino)cyclopropenylidene (BAC) Adduct. Organometallics. 42:1005–1012.
Pedrick EA, Assefa MK, Wakefield ME, Wu G, Hayton TW.  2017.  Uranyl Coordination by the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene. Inorganic Chemistry. 56(11):6638–6644.
Assefa MK, Wu G, Hayton TW.  2020.  Uranyl oxo silylation promoted by silsesquioxane coordination. Journal of the American Chemical Society. 142:8738–8747.
Staun SL, Sergentu D-C, Wu G, Autschbach J, Hayton TW.  2019.  Use of 15N NMR spectroscopy to probe covalency in a thorium nitride. Chem. Sci.. 10:6431-6436.
Hayton TW, Autschbach J.  2025.  Using NMR Spectroscopy to Evaluate Metal–Ligand Bond Covalency for the f Elements. Accounts of Chemical Research. 58:488-498.