Publications
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2025. Using NMR Spectroscopy to Evaluate Metal–Ligand Bond Covalency for the f Elements. Accounts of Chemical Research. 58:488-498.
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2019. Use of 15N NMR spectroscopy to probe covalency in a thorium nitride. Chem. Sci.. 10:6431-6436.
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2023. U-C Bond Insertion, Ring-Opening, and C-H Activation in a Uranium Bis(diisopropylamino)cyclopropenylidene (BAC) Adduct. Organometallics. 42:1005–1012.
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2025. Synthesis, Structure, and 199Hg Chemical Shifts of Mercury 1,5,9-trimesityldipyrromethene (MesDPM) Complexes. Chemistry – A European Journal. 31:e202501460.
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2021. Synthesis of Parent Acetylide and Dicarbide Complexes of Thorium and Uranium and an Examination of Their Electronic Structures. Inorganic Chemistry. 60:15413–15420.
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2026. Synthesis of a Series of Ln(III) (Ln = La, Ce, Lu) Aryl Complexes and Analysis of Their Ln-L Bonding Using Multinuclear NMR Spectroscopy and DFT Calculations. Inorganic Chemistry. 65:14957-14967.
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2019. Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li]2[M(N═CtBuPh)6] (M = Ce, Th). Inorganic Chemistry. 58:12654-12661.
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2021. Synthesis and Electronic Structure Analysis of the Actinide Allenylidenes, [(NR2)3An(CCCPh2)]- (An = U, Th; R = SiMe3). Chemical Science. 12:14383-14388.
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2021. Synthesis and Characterization of Two Uranyl-Aryl “Ate” Complexes. Chemistry – A European Journal. 27:5885-5889.
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2025. Spin-Orbit Effects in a Thallium Borohydride Stabilized by Coordination to Bis(diisopropylamino)Cyclopropenylidene (BAC). Angewandte Chemie International Edition. 64:e202509732.
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2022. Ring-opening of a Thorium Cyclopropenyl Complex Generates a Transient Thorium-bound Carbene. Chem. Commun.. 58:6805-6808.
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2024. Quantifying Actinide–Carbon Bond Covalency in a Uranyl–Aryl Complex Utilizing Solution 13C NMR Spectroscopy. Inorganic Chemistry. 63:9427–9433.
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2020. Probing the Electronic Structure of a Thorium Nitride Complex by Solid-State 15N NMR Spectroscopy. Inorganic Chemistry. 59:10138–10145.
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2021. Homoleptic Perchlorophenyl "Ate" Complexes of Thorium(IV) and Uranium(IV). Inorganic Chemistry. 60:12436–12444.
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2024. Exploring Spin-Orbit Effects in a [Cu6Tl]+ Nanocluster Featuring an Uncommon Tl-H Interaction. Chemistry – A European Journal. 30:e202400390.
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2022. Assessing the 4f Orbital Participation in the Ln–C Bonds of [Li(THF)4][Ln(C6Cl5)4] (Ln = La, Ce). Inorganic Chemistry. 61:15138–15143.
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2024. An Actinide Complex with a Nucleophilic Allenylidene Ligand. Journal of the American Chemical Society. 146:28306–28319.
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2025. 4f-orbital covalency enables a single-crystal-to-single-crystal ring-opening isomerization in a Ce-cyclopropenyl complex.. Nat Chem. 17:961–967.