Publications

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Smiles DE, Wu G, Hrobárik P, Hayton TW.  2017.  Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium. Organometallics. 36:4519–4524.
Pedrick EA, Hrobárik P, Seaman LA, Wu G, Hayton TW.  2016.  Synthesis, structure and bonding of hexaphenyl thorium(iv): observation of a non-octahedral structure. Chem Commun (Camb). 52(4):689-92.
Smiles DE, Wu G, Hayton TW.  2014.  Synthesis of uranium-ligand multiple bonds by cleavage of a trityl protecting group. J Am Chem Soc. 136(1):96-9.
Smiles DE, Wu G, Hayton TW.  2014.  Synthesis of terminal monochalcogenide and dichalcogenide complexes of uranium using polychalcogenides, [En]2- (E = Te, n = 2; E = Se, n = 4), as chalcogen atom transfer reagents. Inorg Chem. 53(19):10240-7.
Kent GT, Yu X, Pauly C, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis of Parent Acetylide and Dicarbide Complexes of Thorium and Uranium and an Examination of Their Electronic Structures. Inorganic Chemistry. ASAP Article
Assefa MK, Wu G, Hayton TW.  2017.  Synthesis of a terminal Ce(iv) oxo complex by photolysis of a Ce(iii) nitrate complex. Chem. Sci.. 8:7873-7878.
Fortier S, Walensky JR, Wu G, Hayton TW.  2011.  Synthesis of a phosphorano-stabilized U(IV)-carbene via one-electron oxidation of a U(III)-ylide adduct. J Am Chem Soc. 133(18):6894-7.
Fortier S, Wu G, Hayton TW.  2010.  Synthesis of a nitrido-substituted analogue of the uranyl ion, [N=U=O]+. J Am Chem Soc. 132(20):6888-9.
Cinco MBaeza, Wu G, Kaltsoyannis N, Hayton T.  2020.  Synthesis of a “Masked” Terminal Zinc Sulfide and its Reactivity with Brønsted and Lewis Acids. Angew. Chem. Int. Ed.. 59:8947-8951.
Hartmann NJ, Wu G, Hayton TW.  2015.  Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide. Angew Chem Int Ed Engl. 54(49):14956-9.
Lewis RA, George SP, Chapovetsky A, Wu G, Figueroa JS, Hayton TW.  2013.  Synthesis of a cobalt(IV) ketimide with a squashed tetrahedral geometry. Chem Commun (Camb). 49(28):2888-90.
Fortier S, Brown JL, Kaltsoyannis N, Wu G, Hayton TW.  2012.  Synthesis, molecular and electronic structure of UV(O)[N(SiMe3)2]3. Inorg Chem. 51(3):1625-33.
Smiles DE, Wu G, Hayton TW.  2016.  Synthesis, Electrochemistry, and Reactivity of the Actinide Trisulfides [K(18-crown-6)][An(η3-S3)(NR2)3] (An = U, Th; R = SiMe3). Inorganic Chemistry. 55:9150-9153.
Cook AW, Nguyen T-AD, Buratto WR, Wu G, Hayton TW.  2016.  Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)4(OAc)2] and [Cu3H(dppm)3(OAc)2]. Inorg. Chem.. 55:12435-12440.
Hayton TW, Wu G.  2008.  Synthesis, characterization, and reactivity of a uranyl β-diketiminate complex. J Am Chem Soc. 130(6):2005-14.
Assefa MK, Sergentu D-C, Seaman LA, Wu G, Autschbach J, Hayton TW.  2019.  Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li]2[M(N═CtBuPh)6] (M = Ce, Th). Inorganic Chemistry. 58:12654-12661.
Brown JL, Fortier S, Wu G, Kaltsoyannis N, Hayton TW.  2013.  Synthesis and spectroscopic and computational characterization of the chalcogenido-substituted analogues of the uranyl ion, [OUE]2+ (E = S, Se). J Am Chem Soc. 135(14):5352-5.
Fortier S, Wu G, Hayton TW.  2009.  Synthesis and redox chemistry of high-valent uranium aryloxides. Inorg Chem. 48(7):3000-11.
Schettini MF, Wu G, Hayton TW.  2012.  Synthesis and reactivity of a uranyl-imidazolyl complex. Chem Commun (Camb). 48(10):1484-6.
Kent G, Yu X, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis and Electronic Structure Analysis of the Actinide Allenylidenes, [(NR2)3An(CCCPh2)]- (An = U, Th; R = SiMe3). Chem. Sci.. Accepted Article:-.
Kent GT, Wu G, Hayton TW.  2019.  Synthesis and Crystallographic Characterization of the Tetravalent Actinide-DOTA Complexes [AnIV8-DOTA)(DMSO)] (An = Th, U). Inorganic Chemistry. 58:8253-8256.
Ordoñez O, Yu X, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis and Characterization of Two Uranyl-Aryl “Ate” Complexes. Chemistry – A European Journal. Early View
Kent GT, Cook AW, Damon PL, Lewis RA, Wu G, Hayton TW.  2021.  Synthesis and Characterization of Two “Tied-Back” Lithium Ketimides and Isolation of a Ketimide-Bridged [Cr2]6+ Dimer with Strong Antiferromagnetic Coupling. Inorganic Chemistry. ASAP Article
Fortier S, Wu G, Hayton TW.  2008.  Synthesis and characterization of three homoleptic alkoxides of uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UVtBu)6], and UVI(OtBu)6. Inorg Chem. 47(11):4752-61.
Lewis RA, Morochnik S, Chapovetsky A, Wu G, Hayton TW.  2012.  Synthesis and characterization of [M2(N=CtBu2)5]- (M=Mn, Fe, Co): metal ketimide complexes with strong metal-metal interactions. Angew Chem Int Ed Engl. 51(51):12772-5.
Cook AW, Jones ZR, Wu G, Teat SJ, Scott SL, Hayton TW.  2019.  Synthesis and Characterization of “Atlas-Sphere” Copper Nanoclusters: New Insights into the Reaction of Cu2+ with Thiols. Inorganic Chemistry. 58:8739-8749.
Lewis RA, Wu G, Hayton TW.  2010.  Synthesis and characterization of an iron(IV) ketimide complex. J Am Chem Soc. 132(37):12814-6.
Cook AW, Hrobárik P, Damon PL, Najera D, Horváth B, Wu G, Hayton TW.  2019.  Synthesis and Characterization of a Linear, Two-Coordinate Pt(II) Ketimide Complex. Inorganic Chemistry. 58:15927-15935.
Nguyen T-AD, Goldsmith BR, Zaman HT, Wu G, Peters B, Hayton TW.  2015.  Synthesis and characterization of a Cu14 hydride cluster supported by neutral donor ligands. Chem Eur J. 21(14):5341-4.
Nguyen T-AD, Cook AW, Wu G, Hayton TW.  2017.  Subnanometer-Sized Copper Clusters: A Critical Re-evaluation of the Synthesis and Characterization of Cu8(MPP)4 (HMPP = 2-Mercapto-5-n-propylpyrimidine). Inorganic Chemistry. 56:8390–8396.
Wright AM, Wu G, Hayton TW.  2010.  Structural characterization of a copper nitrosyl complex with a {CuNO}10 configuration. J Am Chem Soc. 132(41):14336-7.
Lewis RA, Wu G, Hayton TW.  2011.  Stabilizing high-valent metal ions with a ketimide ligand set: synthesis of Mn(N=CtBu2)4. Inorg Chem. 50(10):4660-8.
Schnaars DD, Wu G, Hayton TW.  2011.  Silylation of the uranyl ion using B(C6F5)3-activated Et3SiH. Inorg Chem. 50(19):9642-9.
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Smiles DE, Wu G, Hayton TW.  2014.  Reversible chalcogen-atom transfer to a terminal uranium sulfide. Inorg Chem. 53(24):12683-5.
Cook AW, Wu G, Hayton TW.  2018.  A Re-examination of the Synthesis of Monolayer-Protected Cox(SCH2CH2Ph)m Nanoclusters: Unexpected Formation of a Thiolate-Protected Co(II) T3 Supertetrahedron. Inorganic Chemistry. 57(14):8189–8194.
Pedrick EA, Wu G, Hayton TW.  2014.  Reductive silylation of the uranyl ion with Ph3SiOTf. Inorg Chem. 53(23):12237-9.
Pedrick EA, Wu G, Kaltsoyannis N, Hayton TW.  2014.  Reductive silylation of a uranyl dibenzoylmethanate complex: an example of controlled uranyl oxo ligand cleavage. Chem Sci. 5:3204-3213.
Staun SL, Kent GT, Gomez-Torres A, Wu G, Fortier S, Hayton TW.  2021.  Reductive Coupling of Xylyl Isocyanide Mediated by Low-Valent Uranium. Organometallics. ASAP Article
Schnaars DD, Wu G, Hayton TW.  2009.  Reduction of pentavalent uranyl to U(IV) facilitated by oxo functionalization. J Am Chem Soc. 131(48):17532-3.
Schnaars DD, Wu G, Hayton TW.  2009.  Reactivity of UI4(OEt2)2 with phenols: probing the chemistry of the U-I bond. Dalton Trans. (19):3681-7.
Schnaars DD, Wu G, Hayton TW.  2008.  Reactivity of UH3 with mild oxidants. Dalton Trans. (44):6121-6.
Smiles DE, Wu G, Hayton TW.  2015.  Reactivity of [U(CH2SiMe2NSiMe3)(NR2)2] (R = SiMe3) with elemental chalcogens: towards a better understanding of chalcogen atom transfer in the actinides. New J Chem. 39:7563-7566.
Kent GT, Staun SL, Wu G, Hayton TW.  2020.  Reactivity of [Ce(NR2)3] (R = SiMe3) with Prospective Carbon Atom Transfer Reagents. Organometallics. 39:2375–2382.
Hartmann NJ, Wu G, Hayton TW.  2016.  Reactivity of a Nickel Sulfide with Carbon Monoxide and Nitric Oxide. Journal of the American Chemical Society. 138:12352-12355.
Lewis RA, Smiles DE, Darmon JM, S. Stieber CE, Wu G, Hayton TW.  2013.  Reactivity and Mössbauer spectroscopic characterization of an Fe(IV) ketimide complex and reinvestigation of an Fe(IV) norbornyl complex. Inorg Chem. 52(14):8218-27.
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Nguyen T-AD, Jones ZR, Goldsmith BR, Buratto WR, Wu G, Scott SL, Hayton TW.  2015.  A Cu25 Nanocluster with Partial Cu(0) Character. J Am Chem Soc. 137(41):13319-24.
Wright AM, Irving BJ, Wu G, Meijer AJHM, Hayton TW.  2015.  A copper(I)-arene complex with an unsupported η6 interaction. Angew Chem Int Ed Engl. 54(10):3088-91.
Kent GT, Murillo J, Wu G, Fortier S, Hayton TW.  2020.  Coordination of Uranyl to the Redox-Active Calix[4]pyrrole Ligand. Inorganic Chemistry. 59:8629–8634.
Schettini MF, Wu G, Hayton TW.  2009.  Coordination of N-donor ligands to a uranyl(V) β-diketiminate complex. Inorg Chem. 48(24):11799-808.
Scepaniak JJ, Wu G, Hayton TW.  2012.  Complexes of Cu(I) supported by a tris(ketimine) tripod. Dalton Trans. 41(26):7859-61.
Brown JL, Fortier S, Lewis RA, Wu G, Hayton TW.  2012.  A complete family of terminal uranium chalcogenides, [U(E)(N{SiMe3}2)3]- (E = O, S, Se, Te). J Am Chem Soc. 134(37):15468-75.
Seaman LA, Fortier S, Wu G, Hayton TW.  2011.  Comparison of the redox chemistry of primary and secondary amides of U(IV): isolation of a U(VI) bis(imido) complex or a homoleptic U(VI) amido complex. Inorg Chem. 50(2):636-46.
Seaman LA, Pedrick EA, Tsuchiya T, Wu G, Jakubikova E, Hayton TW.  2013.  Comparison of the reactivity of 2-Li-C6H4CH2NMe2 with MCl4 (M=Th, U): isolation of a thorium aryl complex or a uranium benzyne complex. Angew Chem Int Ed Engl. 52(40):10589-92.
Brown JL, Wu G, Hayton TW.  2013.  Chalcogen Atom Transfer to Uranium(III): Synthesis and Characterization of [(R2N)3U]2(μ-E) and [(R2N)3U]2(μ-η22-S2) (R = SiMe3; E = S, Se, Te). Organometallics. 32:1193-1198.