Publications

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2016
Hartmann NJ, Wu G, Hayton T.W.  2016.  Activation of CS2 by a "masked" terminal nickel sulfide. Dalton Trans. 45:14508-14510.
Damon PL, Wu G, Kaltsoyannis N, Hayton TW.  2016.  Formation of a Ce(IV) Oxo Complex via Inner Sphere Nitrate Reduction. Journal of the American Chemical Society. 138:12743-12746.
Nguyen T-AD, Jones ZR, Leto DF, Wu G, Scott SL, Hayton TW.  2016.  Ligand Exchange-Induced Growth of an Atomically Precise Cu29 Nanocluster from a Smaller Cluster. Chemistry of Materials. 28:8385–8390.
Hartmann NJ, Wu G, Hayton TW.  2016.  Reactivity of a Nickel Sulfide with Carbon Monoxide and Nitric Oxide. Journal of the American Chemical Society. 138:12352-12355.
Cook AW, Nguyen T-AD, Buratto WR, Wu G, Hayton TW.  2016.  Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)4(OAc)2] and [Cu3H(dppm)3(OAc)2]. Inorg. Chem.. 55:12435-12440.
Smiles DE, Wu G, Hayton TW.  2016.  Synthesis, Electrochemistry, and Reactivity of the Actinide Trisulfides [K(18-crown-6)][An(η3-S3)(NR2)3] (An = U, Th; R = SiMe3). Inorganic Chemistry. 55:9150-9153.
Pedrick EA, Hrobárik P, Seaman LA, Wu G, Hayton TW.  2016.  Synthesis, structure and bonding of hexaphenyl thorium(iv): observation of a non-octahedral structure. Chem Commun (Camb). 52(4):689-92.
Smiles DE, Wu G, Hrobárik P, Hayton TW.  2016.  Use of 77Se and 125Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(En){N(SiMe3)2}3]- (E = Se, Te; n = 1, 2) and Their Oxo-Uranium(VI) Congeners. J Am Chem Soc. 138(3):814-25.
2013
Brown JL, Wu G, Hayton TW.  2013.  Chalcogen Atom Transfer to Uranium(III): Synthesis and Characterization of [(R2N)3U]2(μ-E) and [(R2N)3U]2(μ-η22-S2) (R = SiMe3; E = S, Se, Te). Organometallics. 32:1193-1198.
Seaman LA, Pedrick EA, Tsuchiya T, Wu G, Jakubikova E, Hayton TW.  2013.  Comparison of the reactivity of 2-Li-C6H4CH2NMe2 with MCl4 (M=Th, U): isolation of a thorium aryl complex or a uranium benzyne complex. Angew Chem Int Ed Engl. 52(40):10589-92.
Wright AM, Page JS, Scepaniak JJ, Wu G, Hayton TW.  2013.  Divergent Reactivity of TEMPO with MBr3 (M = B, Al). Eur J Inorg Chem. 2013:3817–3820.
Seaman LA, Walensky JR, Wu G, Hayton TW.  2013.  In pursuit of homoleptic actinide alkyl complexes. Inorg Chem. 52(7):3556-64.
Wright AM, Zaman HT, Wu G, Hayton TW.  2013.  Nitric oxide release from a nickel nitrosyl complex induced by one-electron oxidation. Inorg Chem. 52(6):3207-16.
Lewis RA, Smiles DE, Darmon JM, S. Stieber CE, Wu G, Hayton TW.  2013.  Reactivity and Mössbauer spectroscopic characterization of an Fe(IV) ketimide complex and reinvestigation of an Fe(IV) norbornyl complex. Inorg Chem. 52(14):8218-27.
Brown JL, Fortier S, Wu G, Kaltsoyannis N, Hayton TW.  2013.  Synthesis and spectroscopic and computational characterization of the chalcogenido-substituted analogues of the uranyl ion, [OUE]2+ (E = S, Se). J Am Chem Soc. 135(14):5352-5.
Lewis RA, George SP, Chapovetsky A, Wu G, Figueroa JS, Hayton TW.  2013.  Synthesis of a cobalt(IV) ketimide with a squashed tetrahedral geometry. Chem Commun (Camb). 49(28):2888-90.
2012
Schnaars DD, Gaunt AJ, Hayton TW, Jones MB, Kirker I, Kaltsoyannis N, May I, Reilly SD, Scott BL, Wu G.  2012.  Bonding trends traversing the tetravalent actinide series: synthesis, structural, and computational analysis of AnIV(Aracnac)4 complexes (An = Th, U, Np, Pu). Inorg Chem. 51(15):8557-66.
Brown JL, Fortier S, Lewis RA, Wu G, Hayton TW.  2012.  A complete family of terminal uranium chalcogenides, [U(E)(N{SiMe3}2)3]- (E = O, S, Se, Te). J Am Chem Soc. 134(37):15468-75.
Scepaniak JJ, Wu G, Hayton TW.  2012.  Complexes of Cu(I) supported by a tris(ketimine) tripod. Dalton Trans. 41(26):7859-61.
Wright AM, Wu G, Hayton TW.  2012.  Formation of N2O from a nickel nitrosyl: isolation of the cis-[N2O2]2- intermediate. J Am Chem Soc. 134(24):9930-3.
Seaman LA, Wu G, Edelstein N, Lukens WW, Magnani N, Hayton TW.  2012.  Probing the 5f orbital contribution to the bonding in a U(V) ketimide complex. J Am Chem Soc. 134(10):4931-40.
Lewis RA, Morochnik S, Chapovetsky A, Wu G, Hayton TW.  2012.  Synthesis and characterization of [M2(N=CtBu2)5]- (M=Mn, Fe, Co): metal ketimide complexes with strong metal-metal interactions. Angew Chem Int Ed Engl. 51(51):12772-5.
Schettini MF, Wu G, Hayton TW.  2012.  Synthesis and reactivity of a uranyl-imidazolyl complex. Chem Commun (Camb). 48(10):1484-6.
Fortier S, Brown JL, Kaltsoyannis N, Wu G, Hayton TW.  2012.  Synthesis, molecular and electronic structure of UV(O)[N(SiMe3)2]3. Inorg Chem. 51(3):1625-33.
Scepaniak JJ, Wright AM, Lewis RA, Wu G, Hayton TW.  2012.  Tuning the reactivity of TEMPO by coordination to a Lewis acid: isolation and reactivity of MCl31-TEMPO) (M = Fe, Al). J Am Chem Soc. 134(47):19350-3.
2011
Schnaars DD, Wu G, Hayton TW.  2011.  Borane-mediated silylation of a metal-oxo ligand. Inorg Chem. 50(11):4695-7.
Seaman LA, Fortier S, Wu G, Hayton TW.  2011.  Comparison of the redox chemistry of primary and secondary amides of U(IV): isolation of a U(VI) bis(imido) complex or a homoleptic U(VI) amido complex. Inorg Chem. 50(2):636-46.
Schnaars DD, Batista ER, Gaunt AJ, Hayton TW, May I, Reilly SD, Scott BL, Wu G.  2011.  Differences in actinide metal-ligand orbital interactions: comparison of U(IV) and Pu(IV) β-ketoiminate N,O donor complexes. Chem Commun (Camb). 47(27):7647-9.
Brown JL, Mokhtarzadeh CC, Lever JM, Wu G, Hayton TW.  2011.  Facile reduction of a uranyl(VI) β-ketoiminate complex to U(IV) upon oxo silylation. Inorg Chem. 50(11):5105-12.
Fortier S, Walensky JR, Wu G, Hayton TW.  2011.  High-valent uranium alkyls: evidence for the formation of UVI(CH2SiMe3)6. J Am Chem Soc. 133(30):11732-43.
Wright AM, Wu G, Hayton TW.  2011.  Late-metal nitrosyl cations: synthesis and reactivity of [Ni(NO)(MeNO2)3][PF6]. Inorg Chem. 50(22):11746-53.
Fortier S, Kaltsoyannis N, Wu G, Hayton TW.  2011.  Probing the reactivity and electronic structure of a uranium(V) terminal oxo complex. J Am Chem Soc. 133(36):14224-7.
Schnaars DD, Wu G, Hayton TW.  2011.  Silylation of the uranyl ion using B(C6F5)3-activated Et3SiH. Inorg Chem. 50(19):9642-9.
Lewis RA, Wu G, Hayton TW.  2011.  Stabilizing high-valent metal ions with a ketimide ligand set: synthesis of Mn(N=CtBu2)4. Inorg Chem. 50(10):4660-8.
Fortier S, Walensky JR, Wu G, Hayton TW.  2011.  Synthesis of a phosphorano-stabilized U(IV)-carbene via one-electron oxidation of a U(III)-ylide adduct. J Am Chem Soc. 133(18):6894-7.