Publications
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2016. Use of 77Se and 125Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(En){N(SiMe3)2}3]- (E = Se, Te; n = 1, 2) and Their Oxo-Uranium(VI) Congeners. J Am Chem Soc. 138(3):814-25.
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2019. Use of 15N NMR spectroscopy to probe covalency in a thorium nitride. Chem. Sci.. 10:6431-6436.
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2020. Uranyl oxo silylation promoted by silsesquioxane coordination. Journal of the American Chemical Society. 142:8738–8747.
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2017. Uranyl Coordination by the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene. Inorganic Chemistry. 56(11):6638–6644.
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2021. Understanding the Early Stages of Nickel Sulfide Nanocluster Growth: Isolation of Ni3, Ni4, Ni5, and Ni8 Intermediates. Small. 17:2003133.
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2010. U(IV) and U(V) azide complexes supported by amide or aryloxide ligands. Dalton Trans. (2):352-4.
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2012. Tuning the reactivity of TEMPO by coordination to a Lewis acid: isolation and reactivity of MCl3(η1-TEMPO) (M = Fe, Al). J Am Chem Soc. 134(47):19350-3.
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2017. Trapping of an NiII Sulfide by a CoI Fulvene Complex. Organometallics. 36(9):1765–1769.
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2015. Thorium-ligand multiple bonds via reductive deprotection of a trityl group. Chem Sci. 6:3891-3899.
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2017. Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium. Organometallics. 36:4519–4524.
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2016. Synthesis, structure and bonding of hexaphenyl thorium(iv): observation of a non-octahedral structure. Chem Commun (Camb). 52(4):689-92.
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2014. Synthesis of uranium-ligand multiple bonds by cleavage of a trityl protecting group. J Am Chem Soc. 136(1):96-9.
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2014. Synthesis of terminal monochalcogenide and dichalcogenide complexes of uranium using polychalcogenides, [En]2- (E = Te, n = 2; E = Se, n = 4), as chalcogen atom transfer reagents. Inorg Chem. 53(19):10240-7.
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2021. Synthesis of Parent Acetylide and Dicarbide Complexes of Thorium and Uranium and an Examination of Their Electronic Structures. Inorganic Chemistry. 60:15413–15420.
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2021. Synthesis of Bis(trityl)iron(II) and Formation of the Iron(0)-Stabilized o,o-Isomer of Gomberg’s Dimer. Organometallics. 40:4045–4049.
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2017. Synthesis of a terminal Ce(iv) oxo complex by photolysis of a Ce(iii) nitrate complex. Chem. Sci.. 8:7873-7878.
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2011. Synthesis of a phosphorano-stabilized U(IV)-carbene via one-electron oxidation of a U(III)-ylide adduct. J Am Chem Soc. 133(18):6894-7.
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2010. Synthesis of a nitrido-substituted analogue of the uranyl ion, [N=U=O]+. J Am Chem Soc. 132(20):6888-9.
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2021. Synthesis of a Mixed-valent Heterobimetallic Actinide Nitride and an Analysis of its Bonding. Chemical Science. 12:15519-15527.
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2020. Synthesis of a “Masked” Terminal Zinc Sulfide and its Reactivity with Brønsted and Lewis Acids. Angew. Chem. Int. Ed.. 59:8947-8951.
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2015. Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide. Angew Chem Int Ed Engl. 54(49):14956-9.
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2013. Synthesis of a cobalt(IV) ketimide with a squashed tetrahedral geometry. Chem Commun (Camb). 49(28):2888-90.
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2012. Synthesis, molecular and electronic structure of UV(O)[N(SiMe3)2]3. Inorg Chem. 51(3):1625-33.
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2016. Synthesis, Electrochemistry, and Reactivity of the Actinide Trisulfides [K(18-crown-6)][An(η3-S3)(NR2)3] (An = U, Th; R = SiMe3). Inorganic Chemistry. 55:9150-9153.
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2016. Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)4(OAc)2] and [Cu3H(dppm)3(OAc)2]. Inorg. Chem.. 55:12435-12440.
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2008. Synthesis, characterization, and reactivity of a uranyl β-diketiminate complex. J Am Chem Soc. 130(6):2005-14.
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2019. Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li]2[M(N═CtBuPh)6] (M = Ce, Th). Inorganic Chemistry. 58:12654-12661.
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2013. Synthesis and spectroscopic and computational characterization of the chalcogenido-substituted analogues of the uranyl ion, [OUE]2+ (E = S, Se). J Am Chem Soc. 135(14):5352-5.
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2009. Synthesis and redox chemistry of high-valent uranium aryloxides. Inorg Chem. 48(7):3000-11.
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2012. Synthesis and reactivity of a uranyl-imidazolyl complex. Chem Commun (Camb). 48(10):1484-6.
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2021. Synthesis and Electronic Structure Analysis of the Actinide Allenylidenes, [(NR2)3An(CCCPh2)]- (An = U, Th; R = SiMe3). Chemical Science. 12:14383-14388.
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2019. Synthesis and Crystallographic Characterization of the Tetravalent Actinide-DOTA Complexes [AnIV(κ8-DOTA)(DMSO)] (An = Th, U). Inorganic Chemistry. 58:8253-8256.
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2021. Synthesis and Characterization of Two Uranyl-Aryl “Ate” Complexes. Chemistry – A European Journal. 27:5885-5889.
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2021. Synthesis and Characterization of Two “Tied-Back” Lithium Ketimides and Isolation of a Ketimide-Bridged [Cr2]6+ Dimer with Strong Antiferromagnetic Coupling. Inorganic Chemistry. 60:4996–5004.
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2008. Synthesis and characterization of three homoleptic alkoxides of uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UVtBu)6], and UVI(OtBu)6. Inorg Chem. 47(11):4752-61.
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2012. Synthesis and characterization of [M2(N=CtBu2)5]- (M=Mn, Fe, Co): metal ketimide complexes with strong metal-metal interactions. Angew Chem Int Ed Engl. 51(51):12772-5.
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2019. Synthesis and Characterization of “Atlas-Sphere” Copper Nanoclusters: New Insights into the Reaction of Cu2+ with Thiols. Inorganic Chemistry. 58:8739-8749.
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2010. Synthesis and characterization of an iron(IV) ketimide complex. J Am Chem Soc. 132(37):12814-6.
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2019. Synthesis and Characterization of a Linear, Two-Coordinate Pt(II) Ketimide Complex. Inorganic Chemistry. 58:15927-15935.
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2015. Synthesis and characterization of a Cu14 hydride cluster supported by neutral donor ligands. Chem Eur J. 21(14):5341-4.
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2017. Subnanometer-Sized Copper Clusters: A Critical Re-evaluation of the Synthesis and Characterization of Cu8(MPP)4 (HMPP = 2-Mercapto-5-n-propylpyrimidine). Inorganic Chemistry. 56:8390–8396.
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2010. Structural characterization of a copper nitrosyl complex with a {CuNO}10 configuration. J Am Chem Soc. 132(41):14336-7.
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2022. Structural and Spectroscopic Characterization of a Zinc-Bound N-Oxyphthalimide Radical. Inorganic Chemistry. 61:13250–13255.
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2011. Stabilizing high-valent metal ions with a ketimide ligand set: synthesis of Mn(N=CtBu2)4. Inorg Chem. 50(10):4660-8.
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2011. Silylation of the uranyl ion using B(C6F5)3-activated Et3SiH. Inorg Chem. 50(19):9642-9.
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2022. Ring-opening of a Thorium Cyclopropenyl Complex Generates a Transient Thorium-bound Carbene. Chem. Commun.. 58:6805-6808.
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2023. Ring-Opening in the Actinide Cyclopropyl Complexes [Cp3U(2,2-Diphenylcyclopropyl)]n− (n = 0, 1). Organometallics. 42:2347–2352.
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2014. Reversible chalcogen-atom transfer to a terminal uranium sulfide. Inorg Chem. 53(24):12683-5.
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2018. A Re-examination of the Synthesis of Monolayer-Protected Cox(SCH2CH2Ph)m Nanoclusters: Unexpected Formation of a Thiolate-Protected Co(II) T3 Supertetrahedron. Inorganic Chemistry. 57(14):8189–8194.
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2014. Reductive silylation of the uranyl ion with Ph3SiOTf. Inorg Chem. 53(23):12237-9.
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2014. Reductive silylation of a uranyl dibenzoylmethanate complex: an example of controlled uranyl oxo ligand cleavage. Chem Sci. 5:3204-3213.
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2021. Reductive Coupling of Xylyl Isocyanide Mediated by Low-Valent Uranium. Organometallics. 40:2934–2938.
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2009. Reduction of pentavalent uranyl to U(IV) facilitated by oxo functionalization. J Am Chem Soc. 131(48):17532-3.
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2009. Reactivity of UI4(OEt2)2 with phenols: probing the chemistry of the U-I bond. Dalton Trans. (19):3681-7.
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2008. Reactivity of UH3 with mild oxidants. Dalton Trans. (44):6121-6.
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2015. Reactivity of [U(CH2SiMe2NSiMe3)(NR2)2] (R = SiMe3) with elemental chalcogens: towards a better understanding of chalcogen atom transfer in the actinides. New J Chem. 39:7563-7566.
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2020. Reactivity of [Ce(NR2)3] (R = SiMe3) with Prospective Carbon Atom Transfer Reagents. Organometallics. 39:2375–2382.
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2016. Reactivity of a Nickel Sulfide with Carbon Monoxide and Nitric Oxide. Journal of the American Chemical Society. 138:12352-12355.
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2013. Reactivity and Mössbauer spectroscopic characterization of an Fe(IV) ketimide complex and reinvestigation of an Fe(IV) norbornyl complex. Inorg Chem. 52(14):8218-27.
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2024. Quantifying Actinide–Carbon Bond Covalency in a Uranyl–Aryl Complex Utilizing Solution 13C NMR Spectroscopy. Inorganic Chemistry. 63:9427–9433.
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2011. Probing the reactivity and electronic structure of a uranium(V) terminal oxo complex. J Am Chem Soc. 133(36):14224-7.
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2012. Probing the 5f orbital contribution to the bonding in a U(V) ketimide complex. J Am Chem Soc. 134(10):4931-40.
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2022. Photolytic or Oxidative Fragmentation of Trityl Diazeniumdiolate (O2N2CPh3–): Evidence for Both C–N and N–N Bond Cleavage. Inorganic Chemistry. 61:14924–14928.
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2023. Photolytic C-Diazeniumdiolate Disassembly in the β-Diketiminate Complexes [MeLM(O2N2CPh3)] (M = Fe, Co, Cu). Inorganic Chemistry. 62:14064–14071.
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2015. Oxo Ligand Substitution in a Cationic Uranyl Complex: Synergistic Interaction of an Electrophile and a Reductant. Inorg Chem. 54(14):7038-44.
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2010. Oxo ligand silylation in a uranyl β-ketoiminate complex. J Am Chem Soc. 132(21):7248-9.
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2018. Oxidation of the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene upon Ligation to the Uranyl Ion. Inorganic Chemistry. 57(14):8317–8324.
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2014. Oxidation of alcohols and activated alkanes with Lewis acid-activated TEMPO. Inorg Chem. 53(21):11377-87.
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2018. An Organometallic Cu20 Nanocluster: Synthesis, Characterization, Immobilization on Silica, and “Click” Chemistry. J. Am. Chem. Soc.. 140:394-400.
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2023. NO and N2O Release from the Trityl Diazeniumdiolate Complexes [M(O2N2CPh3)3]− (M = Fe, Co). Inorganic Chemistry. 62:4847–4852.
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2013. Nitric oxide release from a nickel nitrosyl complex induced by one-electron oxidation. Inorg Chem. 52(6):3207-16.
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2022. [Ni30S16PEt3)11]: an open-shell nickel sulfide nanocluster with a “metal-like” core. Chem. Sci.. 13:5171-5175.
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2021. [Ni23Se12(PEt3)13] Revisited: Isolation and Characterization of [Ni23Se12Cl3(PEt3)10]. Inorganic Chemistry. 60:17586–17592.
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2008. Mixed-ligand uranyl(V) β-diketiminate/β-diketonate complexes: synthesis and characterization. Inorg Chem. 47(16):7415-23.
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2022. Metal–Metal-Bonded Fe4 Clusters with Slow Magnetic Relaxation. Inorganic Chemistry. 61:9997–10005.
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2014. Mechanistic insights into the formation of N2O by a nickel nitrosyl complex. Inorg Chem. 53(6):3108-16.
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2023. Measuring Metal–Metal Communication in a Series of Ketimide-Bridged [Fe2]6+ Complexes. Inorganic Chemistry. 62:11829–11836.
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2016. Ligand Exchange-Induced Growth of an Atomically Precise Cu29 Nanocluster from a Smaller Cluster. Chemistry of Materials. 28:8385–8390.
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2011. Late-metal nitrosyl cations: synthesis and reactivity of [Ni(NO)(MeNO2)3][PF6]. Inorg Chem. 50(22):11746-53.
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2020. A Ketimide-Stabilized Palladium Nanocluster with a Hexagonal Aromatic Pd7 Core. Inorg. Chem.. 59:1471-1480.
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2010. Isolation of a uranyl amide by "ate" complex formation. Dalton Trans. 39(29):6635-7.
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2013. In pursuit of homoleptic actinide alkyl complexes. Inorg Chem. 52(7):3556-64.
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2009. Homoleptic uranium(IV) alkyl complexes: synthesis and characterization. J Am Chem Soc. 131(42):15512-21.
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2021. Homoleptic Perchlorophenyl "Ate" Complexes of Thorium(IV) and Uranium(IV). Inorganic Chemistry. 60:12436–12444.
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2024. A homoleptic Fe(iv) ketimide complex with a low-lying excited state. Chem. Sci.. Advance Article:-.
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2011. High-valent uranium alkyls: evidence for the formation of UVI(CH2SiMe3)6. J Am Chem Soc. 133(30):11732-43.
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2020. Generation of a Ni3 Phosphinidene Cluster from the Ni(0) Synthon, Ni(η3-CPh3)2. Organometallics. 39:1360–1365.
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2012. Formation of N2O from a nickel nitrosyl: isolation of the cis-[N2O2]2- intermediate. J Am Chem Soc. 134(24):9930-3.
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2016. Formation of a Ce(IV) Oxo Complex via Inner Sphere Nitrate Reduction. Journal of the American Chemical Society. 138:12743-12746.
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2011. Facile reduction of a uranyl(VI) β-ketoiminate complex to U(IV) upon oxo silylation. Inorg Chem. 50(11):5105-12.
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2009. Exploring the effects of reduction or Lewis acid coordination on the U=O bond of the uranyl moiety. Inorg Chem. 48(7):3065-72.
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2024. Exploring Spin-Orbit Effects in a [Cu6Tl]+ Nanocluster Featuring an Uncommon Tl-H Interaction. Chemistry – A European Journal. 30:e202400390.
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2021. Expanding the Nonaqueous Chemistry of Neptunium: Synthesis and Structural Characterization of [Np(NR2)3Cl], [Np(NR2)3Cl]−, and [NpN(R)(SiMe2CH2)2(NR2)]− (R = SiMe3). Inorganic Chemistry. 60:2740–2748.
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2013. Divergent Reactivity of TEMPO with MBr3 (M = B, Al). Eur J Inorg Chem. 2013:3817–3820.
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2023. Dimerization and ring-opening in bis(diisopropylamino)cyclopropenylidene (BAC) mediated by [U(NR2)3(CCPh)] (R = SiMe3). Dalton Transactions. 52:13868-13871.
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2011. Differences in actinide metal-ligand orbital interactions: comparison of U(IV) and Pu(IV) β-ketoiminate N,O donor complexes. Chem Commun (Camb). 47(27):7647-9.
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2015. A Cu25 Nanocluster with Partial Cu(0) Character. J Am Chem Soc. 137(41):13319-24.
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2015. A copper(I)-arene complex with an unsupported η6 interaction. Angew Chem Int Ed Engl. 54(10):3088-91.
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2020. Coordination of Uranyl to the Redox-Active Calix[4]pyrrole Ligand. Inorganic Chemistry. 59:8629–8634.
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2009. Coordination of N-donor ligands to a uranyl(V) β-diketiminate complex. Inorg Chem. 48(24):11799-808.
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2012. Complexes of Cu(I) supported by a tris(ketimine) tripod. Dalton Trans. 41(26):7859-61.
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2012. A complete family of terminal uranium chalcogenides, [U(E)(N{SiMe3}2)3]- (E = O, S, Se, Te). J Am Chem Soc. 134(37):15468-75.
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2011. Comparison of the redox chemistry of primary and secondary amides of U(IV): isolation of a U(VI) bis(imido) complex or a homoleptic U(VI) amido complex. Inorg Chem. 50(2):636-46.
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2013. Comparison of the reactivity of 2-Li-C6H4CH2NMe2 with MCl4 (M=Th, U): isolation of a thorium aryl complex or a uranium benzyne complex. Angew Chem Int Ed Engl. 52(40):10589-92.
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2013. Chalcogen Atom Transfer to Uranium(III): Synthesis and Characterization of [(R2N)3U]2(μ-E) and [(R2N)3U]2(μ-η2:η2-S2) (R = SiMe3; E = S, Se, Te). Organometallics. 32:1193-1198.
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2011. Borane-mediated silylation of a metal-oxo ligand. Inorg Chem. 50(11):4695-7.
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2022. Assessing the 4f Orbital Participation in the Ln–C Bonds of [Li(THF)4][Ln(C6Cl5)4] (Ln = La, Ce). Inorganic Chemistry. 61:15138–15143.
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2016. Activation of CS2 by a "masked" terminal nickel sulfide. Dalton Trans. 45:14508-14510.
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2024. An Actinide Complex with a Nucleophilic Allenylidene Ligand. Journal of the American Chemical Society. ASAP Article