Publications
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2024. Synthesis and characterization of the actinide tosylimido complexes [K(18-crown-6)][An(NSO2-p-tolyl)(NR2)3] (An = U, Th; R = SiMe3). Polyhedron. 249:116787.
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2024. Synthesis and characterization of the actinide tosylimido complexes [K(18-crown-6)][An(NSO2-p-tolyl)(NR2)3] (An = U, Th; R = SiMe3). Polyhedron. 249:116787.
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2023. Ring-Opening in the Actinide Cyclopropyl Complexes [Cp3U(2,2-Diphenylcyclopropyl)]n− (n = 0, 1). Organometallics. 42:2347–2352.
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2022. Periodic TableTalks: An Oasis of Science within a Conference Desert. Inorganic Chemistry. 61:5965-5971.
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2021. Expanding the Nonaqueous Chemistry of Neptunium: Synthesis and Structural Characterization of [Np(NR2)3Cl], [Np(NR2)3Cl]−, and [NpN(R)(SiMe2CH2)2(NR2)]− (R = SiMe3). Inorganic Chemistry. 60:2740–2748.
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2021. Expanding the Nonaqueous Chemistry of Neptunium: Synthesis and Structural Characterization of [Np(NR2)3Cl], [Np(NR2)3Cl]−, and [NpN(R)(SiMe2CH2)2(NR2)]− (R = SiMe3). Inorganic Chemistry. 60:2740–2748.
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2021. Expanding the Nonaqueous Chemistry of Neptunium: Synthesis and Structural Characterization of [Np(NR2)3Cl], [Np(NR2)3Cl]−, and [NpN(R)(SiMe2CH2)2(NR2)]− (R = SiMe3). Inorganic Chemistry. 60:2740–2748.
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2021. Expanding the Nonaqueous Chemistry of Neptunium: Synthesis and Structural Characterization of [Np(NR2)3Cl], [Np(NR2)3Cl]−, and [NpN(R)(SiMe2CH2)2(NR2)]− (R = SiMe3). Inorganic Chemistry. 60:2740–2748.
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2021. Reductive Coupling of Xylyl Isocyanide Mediated by Low-Valent Uranium. Organometallics. 40:2934–2938.
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2021. Synthesis of a Mixed-valent Heterobimetallic Actinide Nitride and an Analysis of its Bonding. Chemical Science. 12:15519-15527.
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2020. Probing the Electronic Structure of a Thorium Nitride Complex by Solid-State 15N NMR Spectroscopy. Inorganic Chemistry. 59:10138–10145.
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2020. Probing the Electronic Structure of a Thorium Nitride Complex by Solid-State 15N NMR Spectroscopy. Inorganic Chemistry. 59:10138–10145.
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2020. Reactivity of [Ce(NR2)3] (R = SiMe3) with Prospective Carbon Atom Transfer Reagents. Organometallics. 39:2375–2382.
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2019. Synthesis and Characterization of “Atlas-Sphere” Copper Nanoclusters: New Insights into the Reaction of Cu2+ with Thiols. Inorganic Chemistry. 58:8739-8749.
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2019. Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li]2[M(N═CtBuPh)6] (M = Ce, Th). Inorganic Chemistry. 58:12654-12661.
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2019. Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li]2[M(N═CtBuPh)6] (M = Ce, Th). Inorganic Chemistry. 58:12654-12661.
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2019. Use of 15N NMR spectroscopy to probe covalency in a thorium nitride. Chem. Sci.. 10:6431-6436.
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2019. Use of 15N NMR spectroscopy to probe covalency in a thorium nitride. Chem. Sci.. 10:6431-6436.
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2018. An Organometallic Cu20 Nanocluster: Synthesis, Characterization, Immobilization on Silica, and “Click” Chemistry. J. Am. Chem. Soc.. 140:394-400.
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2018. Promoting oxo functionalization in the uranyl ion by ligation to ketimides. Journal of Organometallic Chemistry. 857:34-37.
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2017. Lithium Enolates in the Enantioselective Construction of Tetrasubstituted Carbon Centers with Chiral Lithium Amides as Noncovalent Stereodirecting Auxiliaries. Journal of the American Chemical Society. 139:527-533.
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2017. Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium. Organometallics. 36:4519–4524.
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2016. Ligand Exchange-Induced Growth of an Atomically Precise Cu29 Nanocluster from a Smaller Cluster. Chemistry of Materials. 28:8385–8390.
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2016. Perturbation of the O–U–O Angle in Uranyl by Coordination to a 12-Membered Macrocycle. Inorganic Chemistry. 55:5693-5701.
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2016. Synthesis and Reactivity of a U(IV) Dibenzyne Complex. Organometallics. 35:494-502.
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2016. Synthesis and Reactivity of a U(IV) Dibenzyne Complex. Organometallics. 35:494-502.
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2016. Synthesis, Electrochemistry, and Reactivity of the Actinide Trisulfides [K(18-crown-6)][An(η3-S3)(NR2)3] (An = U, Th; R = SiMe3). Inorganic Chemistry. 55:9150-9153.
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2016. Synthesis, structure and bonding of hexaphenyl thorium(iv): observation of a non-octahedral structure. Chem Commun (Camb). 52(4):689-92.
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2015. Coordination chemistry of the actinide elements. McGraw-Hill Yearbook of Science and Technology.
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2015. A Cu25 Nanocluster with Partial Cu(0) Character. J Am Chem Soc. 137(41):13319-24.
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2015. Quantifying the Electron Donor and Acceptor Abilities of the Ketimide Ligands in M(N═CtBu2)4 (M = V, Nb, Ta). Inorg Chem. 54(20):10081-95.
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2015. Reactivity of [U(CH2SiMe2NSiMe3)(NR2)2] (R = SiMe3) with elemental chalcogens: towards a better understanding of chalcogen atom transfer in the actinides. New J Chem. 39:7563-7566.
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2015. Thorium-ligand multiple bonds via reductive deprotection of a trityl group. Chem Sci. 6:3891-3899.
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2014. Reversible chalcogen-atom transfer to a terminal uranium sulfide. Inorg Chem. 53(24):12683-5.
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2014. Synthesis of terminal monochalcogenide and dichalcogenide complexes of uranium using polychalcogenides, [En]2- (E = Te, n = 2; E = Se, n = 4), as chalcogen atom transfer reagents. Inorg Chem. 53(19):10240-7.
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2014. Synthesis of uranium-ligand multiple bonds by cleavage of a trityl protecting group. J Am Chem Soc. 136(1):96-9.
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2013. Comparison of the reactivity of 2-Li-C6H4CH2NMe2 with MCl4 (M=Th, U): isolation of a thorium aryl complex or a uranium benzyne complex. Angew Chem Int Ed Engl. 52(40):10589-92.
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2013. Divergent Reactivity of TEMPO with MBr3 (M = B, Al). Eur J Inorg Chem. 2013:3817–3820.
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2013. Enediolate–Dilithium Amide Mixed Aggregates in the Enantioselective Alkylation of Arylacetic Acids: Structural Studies and a Stereochemical Model. J Am Chem Soc. 135:16853-16864.
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2013. In pursuit of homoleptic actinide alkyl complexes. Inorg Chem. 52(7):3556-64.
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2013. Quantifying the σ and π interactions between U(V) f orbitals and halide, alkyl, alkoxide, amide and ketimide ligands. J Am Chem Soc. 135(29):10742-54.
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2013. A rare uranyl(VI)-alkyl ate complex [Li(DME)1.5]2[UO2(CH2SiMe3)4] and its comparison with a homoleptic uranium(VI)-hexaalkyl. Angew Chem Int Ed Engl. 52(11):3259-63.
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2013. A rare uranyl(VI)-alkyl ate complex [Li(DME)1.5]2[UO2(CH2SiMe3)4] and its comparison with a homoleptic uranium(VI)-hexaalkyl. Angew Chem Int Ed Engl. 52(11):3259-63.
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2013. Reactivity and Mössbauer spectroscopic characterization of an Fe(IV) ketimide complex and reinvestigation of an Fe(IV) norbornyl complex. Inorg Chem. 52(14):8218-27.
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2013. Reactivity and Mössbauer spectroscopic characterization of an Fe(IV) ketimide complex and reinvestigation of an Fe(IV) norbornyl complex. Inorg Chem. 52(14):8218-27.
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2013. Tetrahalide complexes of the [U(NR)2]2+ ion: synthesis, theory, and chlorine K-edge X-ray absorption spectroscopy. J Am Chem Soc. 135(6):2279-90.
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2013. Tetrahalide complexes of the [U(NR)2]2+ ion: synthesis, theory, and chlorine K-edge X-ray absorption spectroscopy. J Am Chem Soc. 135(6):2279-90.
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2013. Tetrahalide complexes of the [U(NR)2]2+ ion: synthesis, theory, and chlorine K-edge X-ray absorption spectroscopy. J Am Chem Soc. 135(6):2279-90.
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2012. Bonding trends traversing the tetravalent actinide series: synthesis, structural, and computational analysis of AnIV(Aracnac)4 complexes (An = Th, U, Np, Pu). Inorg Chem. 51(15):8557-66.
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2012. Bonding trends traversing the tetravalent actinide series: synthesis, structural, and computational analysis of AnIV(Aracnac)4 complexes (An = Th, U, Np, Pu). Inorg Chem. 51(15):8557-66.
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2012. Complexes of Cu(I) supported by a tris(ketimine) tripod. Dalton Trans. 41(26):7859-61.
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2012. A direct route to bis(imido)uranium(V) halides via metathesis of uranium tetrachloride. J Am Chem Soc. 134(24):9876-8.
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2012. A direct route to bis(imido)uranium(V) halides via metathesis of uranium tetrachloride. J Am Chem Soc. 134(24):9876-8.
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2012. Probing the 5f orbital contribution to the bonding in a U(V) ketimide complex. J Am Chem Soc. 134(10):4931-40.
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2012. Synthesis and reactivity of a uranyl-imidazolyl complex. Chem Commun (Camb). 48(10):1484-6.
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2012. Tuning the reactivity of TEMPO by coordination to a Lewis acid: isolation and reactivity of MCl3(η1-TEMPO) (M = Fe, Al). J Am Chem Soc. 134(47):19350-3.
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2011. Borane-mediated silylation of a metal-oxo ligand. Inorg Chem. 50(11):4695-7.
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2011. Comparison of the redox chemistry of primary and secondary amides of U(IV): isolation of a U(VI) bis(imido) complex or a homoleptic U(VI) amido complex. Inorg Chem. 50(2):636-46.
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2011. Differences in actinide metal-ligand orbital interactions: comparison of U(IV) and Pu(IV) β-ketoiminate N,O donor complexes. Chem Commun (Camb). 47(27):7647-9.
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2011. Differences in actinide metal-ligand orbital interactions: comparison of U(IV) and Pu(IV) β-ketoiminate N,O donor complexes. Chem Commun (Camb). 47(27):7647-9.
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2011. Silylation of the uranyl ion using B(C6F5)3-activated Et3SiH. Inorg Chem. 50(19):9642-9.
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2010. Isolation of a uranyl amide by "ate" complex formation. Dalton Trans. 39(29):6635-7.
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2010. Isolation of a uranyl amide by "ate" complex formation. Dalton Trans. 39(29):6635-7.
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2009. Coordination of N-donor ligands to a uranyl(V) β-diketiminate complex. Inorg Chem. 48(24):11799-808.
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2009. Reactivity of UI4(OEt2)2 with phenols: probing the chemistry of the U-I bond. Dalton Trans. (19):3681-7.
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2009. Reduction of pentavalent uranyl to U(IV) facilitated by oxo functionalization. J Am Chem Soc. 131(48):17532-3.
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2008. Low-valent molecular plutonium halide complexes. Inorg Chem. 47(18):8412-9.
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2008. Reactivity of UH3 with mild oxidants. Dalton Trans. (44):6121-6.
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2008. Synthesis and reactivity of bis(imido) uranium(VI) cyclopentadienyl complexes. Chem Commun (Camb). (40):4986-8.
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2008. Synthesis and reactivity of bis(imido) uranium(VI) cyclopentadienyl complexes. Chem Commun (Camb). (40):4986-8.
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2007. An entry route into non-aqueous plutonyl coordination chemistry. Chem Commun (Camb). (16):1659-61.
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2006. Exchange of an imido ligand in bis(imido) complexes of uranium. J Am Chem Soc. 128(39):12622-3.
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2006. Synthesis and reactivity of the imido analogues of the uranyl ion. J Am Chem Soc. 128(32):10549-59.
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2005. Coupling of an aldehyde or ketone to pyridine mediated by a tungsten imido complex. Inorg Chem. 44(25):9506-17.
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2005. Synthesis of imido analogs of the uranyl ion. Science. 310(5756):1941-3.
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2002. Coordination and organometallic chemistry of metal-NO complexes. Chem Rev. 102(4):935-92.