Publications

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Author Title [ Type(Desc)] Year
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Book Chapter
Hayton TW, Kaltsoyannis N.  2018.  Organometallic Actinide Complexes with Novel Oxidation States and Ligand Types. Experimental and Theoretical Approaches to Actinide Chemistry. :181–236.
Journal Article
Schnaars DD, Gaunt AJ, Hayton TW, Jones MB, Kirker I, Kaltsoyannis N, May I, Reilly SD, Scott BL, Wu G.  2012.  Bonding trends traversing the tetravalent actinide series: synthesis, structural, and computational analysis of AnIV(Aracnac)4 complexes (An = Th, U, Np, Pu). Inorg Chem. 51(15):8557-66.
Schnaars DD, Gaunt AJ, Hayton TW, Jones MB, Kirker I, Kaltsoyannis N, May I, Reilly SD, Scott BL, Wu G.  2012.  Bonding trends traversing the tetravalent actinide series: synthesis, structural, and computational analysis of AnIV(Aracnac)4 complexes (An = Th, U, Np, Pu). Inorg Chem. 51(15):8557-66.
Kent GT, Murillo J, Wu G, Fortier S, Hayton TW.  2020.  Coordination of Uranyl to the Redox-Active Calix[4]pyrrole Ligand. Inorganic Chemistry. 59:8629–8634.
Gladfelder J, Ghosh S, Podunavac M, Cook AW, Ma Y, Woltornist RA, Keresztes I, Hayton TW, Collum DB, Zakarian A.  2019.  Enantioselective Alkylation of 2-Alkyl Pyridines Controlled by Organolithium Aggregation. Journal of the American Chemical Society. 141:15024-15028.
Ma Y, Stivala CE, Wright AM, Hayton TW, Liang J, Keresztes I, Lobkovsky E, Collum DB, Zakarian A.  2013.  Enediolate–Dilithium Amide Mixed Aggregates in the Enantioselective Alkylation of Arylacetic Acids: Structural Studies and a Stereochemical Model. J Am Chem Soc. 135:16853-16864.
Damon PL, Wu G, Kaltsoyannis N, Hayton TW.  2016.  Formation of a Ce(IV) Oxo Complex via Inner Sphere Nitrate Reduction. Journal of the American Chemical Society. 138:12743-12746.
Hertler PR, Kautzsch L, Touchton AJ, Wu G, Hayton TW.  2022.  Metal–Metal-Bonded Fe4 Clusters with Slow Magnetic Relaxation. Inorganic Chemistry. ASAP Article
Cinco MÁBaeza, Kräh S, Guzman CF, Wu G, Hayton TW.  2022.  Photolytic or Oxidative Fragmentation of Trityl Diazeniumdiolate (O2N2CPh3): Evidence for Both C–N and N–N Bond Cleavage. Inorganic Chemistry. 61:ASAPArticle.
Sergentu D-C, Kent GT, Staun SL, Yu X, Cho H, Autschbach J, Hayton TW.  2020.  Probing the Electronic Structure of a Thorium Nitride Complex by Solid-State 15N NMR Spectroscopy. Inorganic Chemistry. 59:10138–10145.
Fortier S, Kaltsoyannis N, Wu G, Hayton TW.  2011.  Probing the reactivity and electronic structure of a uranium(V) terminal oxo complex. J Am Chem Soc. 133(36):14224-7.
Seaman LA, Hrobárik P, Schettini MF, Fortier S, Kaupp M, Hayton TW.  2013.  A rare uranyl(VI)-alkyl ate complex [Li(DME)1.5]2[UO2(CH2SiMe3)4] and its comparison with a homoleptic uranium(VI)-hexaalkyl. Angew Chem Int Ed Engl. 52(11):3259-63.
Kent GT, Staun SL, Wu G, Hayton TW.  2020.  Reactivity of [Ce(NR2)3] (R = SiMe3) with Prospective Carbon Atom Transfer Reagents. Organometallics. 39:2375–2382.
Keener M, Hunt C, Carroll TG, Kampel V, Dobrovetsky R, Hayton TW, Ménard G.  2020.  Redox-switchable carboranes for uranium capture and release. Nature. 577:652–655.
Keener M, Hunt C, Carroll TG, Kampel V, Dobrovetsky R, Hayton TW, Ménard G.  2020.  Redox-switchable carboranes for uranium capture and release. Nature. 577:652–655.
Staun SL, Kent GT, Gomez-Torres A, Wu G, Fortier S, Hayton TW.  2021.  Reductive Coupling of Xylyl Isocyanide Mediated by Low-Valent Uranium. Organometallics. 40:2934–2938.
Pedrick EA, Wu G, Kaltsoyannis N, Hayton TW.  2014.  Reductive silylation of a uranyl dibenzoylmethanate complex: an example of controlled uranyl oxo ligand cleavage. Chem Sci. 5:3204-3213.
Kent G, Yu X, Wu G, Autschbach J, Hayton TW.  2022.  Ring-opening of a Thorium Cyclopropenyl Complex Generates a Transient Thorium-bound Carbene. Chem. Commun.. 58:6805-6808.
Keener M, Mattejat M, Zheng S-L, Wu G, Hayton TW, Ménard G.  2022.  Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes. Chem. Sci.. 13:3369-3374.
Kent GT, Cook AW, Damon PL, Lewis RA, Wu G, Hayton TW.  2021.  Synthesis and Characterization of Two “Tied-Back” Lithium Ketimides and Isolation of a Ketimide-Bridged [Cr2]6+ Dimer with Strong Antiferromagnetic Coupling. Inorganic Chemistry. 60:4996–5004.
Kent GT, Wu G, Hayton TW.  2019.  Synthesis and Crystallographic Characterization of the Tetravalent Actinide-DOTA Complexes [AnIV8-DOTA)(DMSO)] (An = Th, U). Inorganic Chemistry. 58:8253-8256.
Kent G, Yu X, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis and Electronic Structure Analysis of the Actinide Allenylidenes, [(NR2)3An(CCCPh2)]- (An = U, Th; R = SiMe3). Chemical Science. 12:14383-14388.
Brown JL, Fortier S, Wu G, Kaltsoyannis N, Hayton TW.  2013.  Synthesis and spectroscopic and computational characterization of the chalcogenido-substituted analogues of the uranyl ion, [OUE]2+ (E = S, Se). J Am Chem Soc. 135(14):5352-5.
Fortier S, Brown JL, Kaltsoyannis N, Wu G, Hayton TW.  2012.  Synthesis, molecular and electronic structure of UV(O)[N(SiMe3)2]3. Inorg Chem. 51(3):1625-33.
Cinco MBaeza, Wu G, Kaltsoyannis N, Hayton T.  2020.  Synthesis of a “Masked” Terminal Zinc Sulfide and its Reactivity with Brønsted and Lewis Acids. Angew. Chem. Int. Ed.. 59:8947-8951.
Kent GT, Yu X, Pauly C, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis of Parent Acetylide and Dicarbide Complexes of Thorium and Uranium and an Examination of Their Electronic Structures. Inorganic Chemistry. 60:15413–15420.
Spencer LP, Yang P, Minasian SG, Jilek RE, Batista ER, Boland KS, Boncella JM, Conradson SD, Clark DL, Hayton TW et al..  2013.  Tetrahalide complexes of the [U(NR)2]2+ ion: synthesis, theory, and chlorine K-edge X-ray absorption spectroscopy. J Am Chem Soc. 135(6):2279-90.
Smiles DE, Wu G, Kaltsoyannis N, Hayton TW.  2015.  Thorium-ligand multiple bonds via reductive deprotection of a trityl group. Chem Sci. 6:3891-3899.