Publications

Found results
[ Author(Desc)] Title Type Year
A B C D E F G H I J K L M N O P Q R S T U V W X Y Z 
C
Cinco MBaeza, Wu G, Kaltsoyannis N, Hayton T.  2020.  Synthesis of a “Masked” Terminal Zinc Sulfide and its Reactivity with Brønsted and Lewis Acids. Angew. Chem. Int. Ed.. 59:8947-8951.
Cinco MÁBaeza, Hayton T.  2020.  Progress Toward the Isolation of Late Metal Terminal Sulfides. European Journal of Inorganic Chemistry. Accepted Article
Cook AW, Wu G, Hayton TW.  2018.  A Re-examination of the Synthesis of Monolayer-Protected Cox(SCH2CH2Ph)m Nanoclusters: Unexpected Formation of a Thiolate-Protected Co(II) T3 Supertetrahedron. Inorganic Chemistry. 57(14):8189–8194.
Cook AW, Hrobárik P, Damon PL, Najera D, Horváth B, Wu G, Hayton TW.  2019.  Synthesis and Characterization of a Linear, Two-Coordinate Pt(II) Ketimide Complex. Inorganic Chemistry. 58:15927-15935.
Cook AW, Hayton TW.  2018.  Case Studies in Nanocluster Synthesis and Characterization: Challenges and Opportunities. Accounts of Chemical Research. 51:2456-2464.
Cook AW, Nguyen T-AD, Buratto WR, Wu G, Hayton TW.  2016.  Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)4(OAc)2] and [Cu3H(dppm)3(OAc)2]. Inorg. Chem.. 55:12435-12440.
Cook AW, Bocarsly JD, Lewis RA, Touchton AJ, Morochnik S, Hayton TW.  2020.  An Iron Ketimide Single-molecule Magnet [Fe4(N=CPh2)6] with Suppressed Through-barrier Relaxation. Chem. Sci.. 11:4753-4757.
Cook AW, Hrobárik P, Damon PL, Wu G, Hayton TW.  2020.  A Ketimide-Stabilized Palladium Nanocluster with a Hexagonal Aromatic Pd7 Core. Inorg. Chem.. 59:1471-1480.
Cook AW, Jones ZR, Wu G, Scott SL, Hayton TW.  2018.  An Organometallic Cu20 Nanocluster: Synthesis, Characterization, Immobilization on Silica, and “Click” Chemistry. J. Am. Chem. Soc.. 140:394-400.
Cook AW, Jones ZR, Wu G, Teat SJ, Scott SL, Hayton TW.  2019.  Synthesis and Characterization of “Atlas-Sphere” Copper Nanoclusters: New Insights into the Reaction of Cu2+ with Thiols. Inorganic Chemistry. 58:8739-8749.
F
Fortier S, Wu G, Hayton TW.  2009.  Synthesis and redox chemistry of high-valent uranium aryloxides. Inorg Chem. 48(7):3000-11.
Fortier S, Walensky JR, Wu G, Hayton TW.  2011.  High-valent uranium alkyls: evidence for the formation of UVI(CH2SiMe3)6. J Am Chem Soc. 133(30):11732-43.
Fortier S, Brown JL, Kaltsoyannis N, Wu G, Hayton TW.  2012.  Synthesis, molecular and electronic structure of UV(O)[N(SiMe3)2]3. Inorg Chem. 51(3):1625-33.
Fortier S, Walensky JR, Wu G, Hayton TW.  2011.  Synthesis of a phosphorano-stabilized U(IV)-carbene via one-electron oxidation of a U(III)-ylide adduct. J Am Chem Soc. 133(18):6894-7.
Fortier S, Wu G, Hayton TW.  2010.  U(IV) and U(V) azide complexes supported by amide or aryloxide ligands. Dalton Trans. (2):352-4.
Fortier S, Kaltsoyannis N, Wu G, Hayton TW.  2011.  Probing the reactivity and electronic structure of a uranium(V) terminal oxo complex. J Am Chem Soc. 133(36):14224-7.
Fortier S, Melot BC, Wu G, Hayton TW.  2009.  Homoleptic uranium(IV) alkyl complexes: synthesis and characterization. J Am Chem Soc. 131(42):15512-21.
Fortier S, Hayton TW.  2010.  Oxo ligand functionalization in the uranyl ion (UO22+). Coord Chem Rev. 254:197-214.
Fortier S, Wu G, Hayton TW.  2010.  Synthesis of a nitrido-substituted analogue of the uranyl ion, [N=U=O]+. J Am Chem Soc. 132(20):6888-9.
Fortier S, Wu G, Hayton TW.  2008.  Synthesis and characterization of three homoleptic alkoxides of uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UVtBu)6], and UVI(OtBu)6. Inorg Chem. 47(11):4752-61.
H
Hartmann NJ, Wu G, Hayton TW.  2017.  Trapping of an NiII Sulfide by a CoI Fulvene Complex. Organometallics. 36(9):1765–1769.
Hartmann NJ, Wu G, Hayton TW.  2016.  Reactivity of a Nickel Sulfide with Carbon Monoxide and Nitric Oxide. Journal of the American Chemical Society. 138:12352-12355.
Hartmann NJ, Wu G, Hayton TW.  2015.  Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide. Angew Chem Int Ed Engl. 54(49):14956-9.
Hartmann NJ, Wu G., Hayton TW.  2018.  Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N2O reduction. Chem. Sci.. 9(31):6580-6588.
Hartmann NJ, Wu G, Hayton T.W.  2016.  Activation of CS2 by a "masked" terminal nickel sulfide. Dalton Trans. 45:14508-14510.
Hayton TW, W. McNeil S, Patrick BO, Legzdins P.  2003.  Toward binary nitrosyls: distinctly bent Fe-N-O linkages in base-stabilized Fe(NO)3+ complexes. J Am Chem Soc. 125(42):12935-44.
Hayton TW, Patrick BO, Legzdins P.  2004.  Reactivity of (trimpsi)V(NO)X2 Complexes (X = Cl, Br, I; trimpsi = tBuSi(CH2PMe2)3). Synthesis of the First Group 5 Alkyl Nitrosyls. Organometallics. 23:657-664.
Hayton TW, Boncella JM, Scott BL, Batista ER, P. Hay J.  2006.  Synthesis and reactivity of the imido analogues of the uranyl ion. J Am Chem Soc. 128(32):10549-59.
Hayton TW, Legzdins P, W. Sharp B.  2002.  Coordination and organometallic chemistry of metal-NO complexes. Chem Rev. 102(4):935-92.
Hayton TW, Wu G.  2008.  Mixed-ligand uranyl(V) β-diketiminate/β-diketonate complexes: synthesis and characterization. Inorg Chem. 47(16):7415-23.
Hayton TW, Wu G.  2009.  Exploring the effects of reduction or Lewis acid coordination on the U=O bond of the uranyl moiety. Inorg Chem. 48(7):3065-72.
Hayton TW, Patrick BO, Legzdins P, W. McNeil S.  2004.  The solid-state molecular structure of W(NO)3Cl3 and the nature of its W-NO bonding. Can J Chem. 82:285-292.
Hayton TW, Boncella JM, Scott BL, Batista ER.  2006.  Exchange of an imido ligand in bis(imido) complexes of uranium. J Am Chem Soc. 128(39):12622-3.
Hayton TW, Kaltsoyannis N.  2018.  Organometallic Actinide Complexes with Novel Oxidation States and Ligand Types. Experimental and Theoretical Approaches to Actinide Chemistry. :181–236.
Hayton TW, Legzdins P, Rettig SJ.  2002.  Di-μ-methoxy-bis[(η5-cyclopentadienyl)(nitrosyl-κ-N)(trimethylsilylmethyl)molybdenum(II)]. Acta Crystallogr C. 58(Pt 7):m377-8.
Hayton TW, Patrick BO, Legzdins P.  2004.  New details concerning the reactions of nitric oxide with vanadium tetrachloride. Inorg Chem. 43(22):7227-33.
Hayton TW.  2018.  Understanding the origins of Oyl-U-Oyl bending in the uranyl (UO22+) ion. Dalton Trans.. 47:1003-1009.
Hayton TW, P. Daff J, Legzdins P, Rettig SJ, Patrick BO.  2002.  Synthesis, characterization, and solution redox properties of (trimpsi)M(CO)2(NO) complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3]. Inorg Chem. 41(16):4114-26.
Hayton TW.  2010.  Metal-ligand multiple bonding in uranium: structure and reactivity. Dalton Trans. 39(5):1145-58.
Hayton TW, Boncella JM, Scott BL, Abboud KA, Mills RC.  2005.  Coupling of an aldehyde or ketone to pyridine mediated by a tungsten imido complex. Inorg Chem. 44(25):9506-17.
Hayton TW.  2013.  Recent developments in actinide-ligand multiple bonding. Chem Commun (Camb). 49(29):2956-73.
Hayton TW, Wu G.  2008.  Synthesis, characterization, and reactivity of a uranyl β-diketiminate complex. J Am Chem Soc. 130(6):2005-14.
Hayton TW, Legzdins P, Patrick BO.  2002.  Differing reactivities of (trimpsi)M(CO)2(NO) complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3] with halogens and halogen sources. Inorg Chem. 41(21):5388-96.
Hayton TW.  2013.  Uranium chemistry: an actinide milestone. Nat Chem. 5(6):451-2.
Hayton TW, Boncella JM, Scott BL, Palmer PD, Batista ER, P. Hay J.  2005.  Synthesis of imido analogs of the uranyl ion. Science. 310(5756):1941-3.
Hayton TW, Legzdins P, Rettig SJ.  2002.  5-cyclopentadienyl)(p-fluorophenoxo)(nitrosyl)(trimethylsilylmethyl)molybdenum(II). Acta Crystallogr C. 58(Pt 2):m68-9.
S
Scepaniak JJ, Wright AM, Lewis RA, Wu G, Hayton TW.  2012.  Tuning the reactivity of TEMPO by coordination to a Lewis acid: isolation and reactivity of MCl31-TEMPO) (M = Fe, Al). J Am Chem Soc. 134(47):19350-3.
Scepaniak JJ, Wu G, Hayton TW.  2012.  Complexes of Cu(I) supported by a tris(ketimine) tripod. Dalton Trans. 41(26):7859-61.
Schettini MF, Wu G, Hayton TW.  2012.  Synthesis and reactivity of a uranyl-imidazolyl complex. Chem Commun (Camb). 48(10):1484-6.
Schettini MF, Wu G, Hayton TW.  2009.  Coordination of N-donor ligands to a uranyl(V) β-diketiminate complex. Inorg Chem. 48(24):11799-808.
Schnaars DD, Batista ER, Gaunt AJ, Hayton TW, May I, Reilly SD, Scott BL, Wu G.  2011.  Differences in actinide metal-ligand orbital interactions: comparison of U(IV) and Pu(IV) β-ketoiminate N,O donor complexes. Chem Commun (Camb). 47(27):7647-9.
Schnaars DD, Wu G, Hayton TW.  2009.  Reduction of pentavalent uranyl to U(IV) facilitated by oxo functionalization. J Am Chem Soc. 131(48):17532-3.
Schnaars DD, Wu G, Hayton TW.  2011.  Silylation of the uranyl ion using B(C6F5)3-activated Et3SiH. Inorg Chem. 50(19):9642-9.
Schnaars DD, Wu G, Hayton TW.  2009.  Reactivity of UI4(OEt2)2 with phenols: probing the chemistry of the U-I bond. Dalton Trans. (19):3681-7.
Schnaars DD, Gaunt AJ, Hayton TW, Jones MB, Kirker I, Kaltsoyannis N, May I, Reilly SD, Scott BL, Wu G.  2012.  Bonding trends traversing the tetravalent actinide series: synthesis, structural, and computational analysis of AnIV(Aracnac)4 complexes (An = Th, U, Np, Pu). Inorg Chem. 51(15):8557-66.
Schnaars DD, Wu G, Hayton TW.  2011.  Borane-mediated silylation of a metal-oxo ligand. Inorg Chem. 50(11):4695-7.
Schnaars DD, Wu G, Hayton TW.  2008.  Reactivity of UH3 with mild oxidants. Dalton Trans. (44):6121-6.
Seaman LA, Pedrick EA, Wu G, Hayton TW.  2018.  Promoting oxo functionalization in the uranyl ion by ligation to ketimides. Journal of Organometallic Chemistry. 857:34-37.
Seaman LA, Schnaars DD, Wu G, Hayton TW.  2010.  Isolation of a uranyl amide by "ate" complex formation. Dalton Trans. 39(29):6635-7.
Seaman LA, Walensky JR, Wu G, Hayton TW.  2013.  In pursuit of homoleptic actinide alkyl complexes. Inorg Chem. 52(7):3556-64.
Seaman LA, Pedrick EA, Tsuchiya T, Wu G, Jakubikova E, Hayton TW.  2013.  Comparison of the reactivity of 2-Li-C6H4CH2NMe2 with MCl4 (M=Th, U): isolation of a thorium aryl complex or a uranium benzyne complex. Angew Chem Int Ed Engl. 52(40):10589-92.
Seaman LA, Wu G, Edelstein N, Lukens WW, Magnani N, Hayton TW.  2012.  Probing the 5f orbital contribution to the bonding in a U(V) ketimide complex. J Am Chem Soc. 134(10):4931-40.
Seaman LA, Fortier S, Wu G, Hayton TW.  2011.  Comparison of the redox chemistry of primary and secondary amides of U(IV): isolation of a U(VI) bis(imido) complex or a homoleptic U(VI) amido complex. Inorg Chem. 50(2):636-46.
Seaman LA, Hrobárik P, Schettini MF, Fortier S, Kaupp M, Hayton TW.  2013.  A rare uranyl(VI)-alkyl ate complex [Li(DME)1.5]2[UO2(CH2SiMe3)4] and its comparison with a homoleptic uranium(VI)-hexaalkyl. Angew Chem Int Ed Engl. 52(11):3259-63.
Sergentu D-C, Kent GT, Staun SL, Yu X, Cho H, Autschbach J, Hayton TW.  2020.  Probing the Electronic Structure of a Thorium Nitride Complex by Solid-State 15N NMR Spectroscopy. Inorganic Chemistry. 59:10138–10145.
Smiles DE, Wu G, Kaltsoyannis N, Hayton TW.  2015.  Thorium-ligand multiple bonds via reductive deprotection of a trityl group. Chem Sci. 6:3891-3899.
Smiles DE, Wu G, Hayton TW.  2014.  Synthesis of terminal monochalcogenide and dichalcogenide complexes of uranium using polychalcogenides, [En]2- (E = Te, n = 2; E = Se, n = 4), as chalcogen atom transfer reagents. Inorg Chem. 53(19):10240-7.
Smiles DE, Wu G, Hayton TW.  2015.  Reactivity of [U(CH2SiMe2NSiMe3)(NR2)2] (R = SiMe3) with elemental chalcogens: towards a better understanding of chalcogen atom transfer in the actinides. New J Chem. 39:7563-7566.
Smiles DE, Hayton TW.  2015.  Coordination chemistry of the actinide elements. McGraw-Hill Yearbook of Science and Technology.
Smiles DE, Wu G, Hayton TW.  2014.  Reversible chalcogen-atom transfer to a terminal uranium sulfide. Inorg Chem. 53(24):12683-5.
Smiles DE, Wu G, Hayton TW.  2014.  Synthesis of uranium-ligand multiple bonds by cleavage of a trityl protecting group. J Am Chem Soc. 136(1):96-9.
Smiles DE, Wu G, Hrobárik P, Hayton TW.  2016.  Use of 77Se and 125Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(En){N(SiMe3)2}3]- (E = Se, Te; n = 1, 2) and Their Oxo-Uranium(VI) Congeners. J Am Chem Soc. 138(3):814-25.
Smiles DE, Wu G, Hrobárik P, Hayton TW.  2017.  Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium. Organometallics. 36:4519–4524.
Smiles DE, Wu G, Hayton TW.  2016.  Synthesis, Electrochemistry, and Reactivity of the Actinide Trisulfides [K(18-crown-6)][An(η3-S3)(NR2)3] (An = U, Th; R = SiMe3). Inorganic Chemistry. 55:9150-9153.
Spencer LP, Yang P, Minasian SG, Jilek RE, Batista ER, Boland KS, Boncella JM, Conradson SD, Clark DL, Hayton TW et al..  2013.  Tetrahalide complexes of the [U(NR)2]2+ ion: synthesis, theory, and chlorine K-edge X-ray absorption spectroscopy. J Am Chem Soc. 135(6):2279-90.
Spencer LP, Gdula RL, Hayton TW, Scott BL, Boncella JM.  2008.  Synthesis and reactivity of bis(imido) uranium(VI) cyclopentadienyl complexes. Chem Commun (Camb). (40):4986-8.
Staun SL, Stevens LM, Smiles DE, Goodwin CAP, Billow BS, Scott BL, Wu G, Tondreau AM, Gaunt AJ, Hayton TW.  2021.  Expanding the Nonaqueous Chemistry of Neptunium: Synthesis and Structural Characterization of [Np(NR2)3Cl], [Np(NR2)3Cl]−, and [NpN(R)(SiMe2CH2)2(NR2)]− (R = SiMe3). Inorganic Chemistry. ASAP Article
Staun SL, Sergentu D-C, Wu G, Autschbach J, Hayton TW.  2019.  Use of 15N NMR spectroscopy to probe covalency in a thorium nitride. Chem. Sci.. 10:6431-6436.