Publications

Found results
Author Title [ Type(Asc)] Year
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Journal Article
Smiles DE, Wu G, Hrobárik P, Hayton TW.  2016.  Use of 77Se and 125Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(En){N(SiMe3)2}3]- (E = Se, Te; n = 1, 2) and Their Oxo-Uranium(VI) Congeners. J Am Chem Soc. 138(3):814-25.
Staun SL, Sergentu D-C, Wu G, Autschbach J, Hayton TW.  2019.  Use of 15N NMR spectroscopy to probe covalency in a thorium nitride. Chem. Sci.. 10:6431-6436.
Assefa MK, Wu G, Hayton TW.  2020.  Uranyl oxo silylation promoted by silsesquioxane coordination. Journal of the American Chemical Society. 142:8738–8747.
Pedrick EA, Assefa MK, Wakefield ME, Wu G, Hayton TW.  2017.  Uranyl Coordination by the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene. Inorganic Chemistry. 56(11):6638–6644.
Touchton AJ, Wu G, Hayton TW.  2020.  Understanding the Early Stages of Nickel Sulfide Nanocluster Growth: Isolation of Ni3, Ni4, Ni5, and Ni8 Intermediates. Small. Early View
Fortier S, Wu G, Hayton TW.  2010.  U(IV) and U(V) azide complexes supported by amide or aryloxide ligands. Dalton Trans. (2):352-4.
Scepaniak JJ, Wright AM, Lewis RA, Wu G, Hayton TW.  2012.  Tuning the reactivity of TEMPO by coordination to a Lewis acid: isolation and reactivity of MCl31-TEMPO) (M = Fe, Al). J Am Chem Soc. 134(47):19350-3.
Hartmann NJ, Wu G, Hayton TW.  2017.  Trapping of an NiII Sulfide by a CoI Fulvene Complex. Organometallics. 36(9):1765–1769.
Smiles DE, Wu G, Kaltsoyannis N, Hayton TW.  2015.  Thorium-ligand multiple bonds via reductive deprotection of a trityl group. Chem Sci. 6:3891-3899.
Smiles DE, Wu G, Hrobárik P, Hayton TW.  2017.  Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium. Organometallics. 36:4519–4524.
Pedrick EA, Hrobárik P, Seaman LA, Wu G, Hayton TW.  2016.  Synthesis, structure and bonding of hexaphenyl thorium(iv): observation of a non-octahedral structure. Chem Commun (Camb). 52(4):689-92.
Smiles DE, Wu G, Hayton TW.  2014.  Synthesis of uranium-ligand multiple bonds by cleavage of a trityl protecting group. J Am Chem Soc. 136(1):96-9.
Smiles DE, Wu G, Hayton TW.  2014.  Synthesis of terminal monochalcogenide and dichalcogenide complexes of uranium using polychalcogenides, [En]2- (E = Te, n = 2; E = Se, n = 4), as chalcogen atom transfer reagents. Inorg Chem. 53(19):10240-7.
Assefa MK, Wu G, Hayton TW.  2017.  Synthesis of a terminal Ce(iv) oxo complex by photolysis of a Ce(iii) nitrate complex. Chem. Sci.. 8:7873-7878.
Fortier S, Walensky JR, Wu G, Hayton TW.  2011.  Synthesis of a phosphorano-stabilized U(IV)-carbene via one-electron oxidation of a U(III)-ylide adduct. J Am Chem Soc. 133(18):6894-7.
Fortier S, Wu G, Hayton TW.  2010.  Synthesis of a nitrido-substituted analogue of the uranyl ion, [N=U=O]+. J Am Chem Soc. 132(20):6888-9.
Cinco MBaeza, Wu G, Kaltsoyannis N, Hayton T.  2020.  Synthesis of a “Masked” Terminal Zinc Sulfide and its Reactivity with Brønsted and Lewis Acids. Angew. Chem. Int. Ed.. 59:8947-8951.
Hartmann NJ, Wu G, Hayton TW.  2015.  Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide. Angew Chem Int Ed Engl. 54(49):14956-9.
Lewis RA, George SP, Chapovetsky A, Wu G, Figueroa JS, Hayton TW.  2013.  Synthesis of a cobalt(IV) ketimide with a squashed tetrahedral geometry. Chem Commun (Camb). 49(28):2888-90.
Fortier S, Brown JL, Kaltsoyannis N, Wu G, Hayton TW.  2012.  Synthesis, molecular and electronic structure of UV(O)[N(SiMe3)2]3. Inorg Chem. 51(3):1625-33.
Smiles DE, Wu G, Hayton TW.  2016.  Synthesis, Electrochemistry, and Reactivity of the Actinide Trisulfides [K(18-crown-6)][An(η3-S3)(NR2)3] (An = U, Th; R = SiMe3). Inorganic Chemistry. 55:9150-9153.
Cook AW, Nguyen T-AD, Buratto WR, Wu G, Hayton TW.  2016.  Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)4(OAc)2] and [Cu3H(dppm)3(OAc)2]. Inorg. Chem.. 55:12435-12440.
Hayton TW, Wu G.  2008.  Synthesis, characterization, and reactivity of a uranyl β-diketiminate complex. J Am Chem Soc. 130(6):2005-14.
Assefa MK, Sergentu D-C, Seaman LA, Wu G, Autschbach J, Hayton TW.  2019.  Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li]2[M(N═CtBuPh)6] (M = Ce, Th). Inorganic Chemistry. 58:12654-12661.
Brown JL, Fortier S, Wu G, Kaltsoyannis N, Hayton TW.  2013.  Synthesis and spectroscopic and computational characterization of the chalcogenido-substituted analogues of the uranyl ion, [OUE]2+ (E = S, Se). J Am Chem Soc. 135(14):5352-5.
Fortier S, Wu G, Hayton TW.  2009.  Synthesis and redox chemistry of high-valent uranium aryloxides. Inorg Chem. 48(7):3000-11.
Schettini MF, Wu G, Hayton TW.  2012.  Synthesis and reactivity of a uranyl-imidazolyl complex. Chem Commun (Camb). 48(10):1484-6.
Kent GT, Wu G, Hayton TW.  2019.  Synthesis and Crystallographic Characterization of the Tetravalent Actinide-DOTA Complexes [AnIV8-DOTA)(DMSO)] (An = Th, U). Inorganic Chemistry. 58:8253-8256.
Ordoñez O, Yu X, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis and Characterization of Two Uranyl-Aryl “Ate” Complexes. Chemistry – A European Journal. Early View
Kent GT, Cook AW, Damon PL, Lewis RA, Wu G, Hayton TW.  2021.  Synthesis and Characterization of Two “Tied-Back” Lithium Ketimides and Isolation of a Ketimide-Bridged [Cr2]6+ Dimer with Strong Antiferromagnetic Coupling. Inorganic Chemistry. ASAP Article
Fortier S, Wu G, Hayton TW.  2008.  Synthesis and characterization of three homoleptic alkoxides of uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UVtBu)6], and UVI(OtBu)6. Inorg Chem. 47(11):4752-61.
Lewis RA, Morochnik S, Chapovetsky A, Wu G, Hayton TW.  2012.  Synthesis and characterization of [M2(N=CtBu2)5]- (M=Mn, Fe, Co): metal ketimide complexes with strong metal-metal interactions. Angew Chem Int Ed Engl. 51(51):12772-5.
Cook AW, Jones ZR, Wu G, Teat SJ, Scott SL, Hayton TW.  2019.  Synthesis and Characterization of “Atlas-Sphere” Copper Nanoclusters: New Insights into the Reaction of Cu2+ with Thiols. Inorganic Chemistry. 58:8739-8749.
Lewis RA, Wu G, Hayton TW.  2010.  Synthesis and characterization of an iron(IV) ketimide complex. J Am Chem Soc. 132(37):12814-6.
Cook AW, Hrobárik P, Damon PL, Najera D, Horváth B, Wu G, Hayton TW.  2019.  Synthesis and Characterization of a Linear, Two-Coordinate Pt(II) Ketimide Complex. Inorganic Chemistry. 58:15927-15935.
Nguyen T-AD, Goldsmith BR, Zaman HT, Wu G, Peters B, Hayton TW.  2015.  Synthesis and characterization of a Cu14 hydride cluster supported by neutral donor ligands. Chem Eur J. 21(14):5341-4.
Nguyen T-AD, Cook AW, Wu G, Hayton TW.  2017.  Subnanometer-Sized Copper Clusters: A Critical Re-evaluation of the Synthesis and Characterization of Cu8(MPP)4 (HMPP = 2-Mercapto-5-n-propylpyrimidine). Inorganic Chemistry. 56:8390–8396.
Wright AM, Wu G, Hayton TW.  2010.  Structural characterization of a copper nitrosyl complex with a {CuNO}10 configuration. J Am Chem Soc. 132(41):14336-7.
Lewis RA, Wu G, Hayton TW.  2011.  Stabilizing high-valent metal ions with a ketimide ligand set: synthesis of Mn(N=CtBu2)4. Inorg Chem. 50(10):4660-8.
Schnaars DD, Wu G, Hayton TW.  2011.  Silylation of the uranyl ion using B(C6F5)3-activated Et3SiH. Inorg Chem. 50(19):9642-9.
Smiles DE, Wu G, Hayton TW.  2014.  Reversible chalcogen-atom transfer to a terminal uranium sulfide. Inorg Chem. 53(24):12683-5.
Cook AW, Wu G, Hayton TW.  2018.  A Re-examination of the Synthesis of Monolayer-Protected Cox(SCH2CH2Ph)m Nanoclusters: Unexpected Formation of a Thiolate-Protected Co(II) T3 Supertetrahedron. Inorganic Chemistry. 57(14):8189–8194.
Pedrick EA, Wu G, Hayton TW.  2014.  Reductive silylation of the uranyl ion with Ph3SiOTf. Inorg Chem. 53(23):12237-9.
Pedrick EA, Wu G, Kaltsoyannis N, Hayton TW.  2014.  Reductive silylation of a uranyl dibenzoylmethanate complex: an example of controlled uranyl oxo ligand cleavage. Chem Sci. 5:3204-3213.
Schnaars DD, Wu G, Hayton TW.  2009.  Reduction of pentavalent uranyl to U(IV) facilitated by oxo functionalization. J Am Chem Soc. 131(48):17532-3.
Schnaars DD, Wu G, Hayton TW.  2009.  Reactivity of UI4(OEt2)2 with phenols: probing the chemistry of the U-I bond. Dalton Trans. (19):3681-7.
Schnaars DD, Wu G, Hayton TW.  2008.  Reactivity of UH3 with mild oxidants. Dalton Trans. (44):6121-6.
Smiles DE, Wu G, Hayton TW.  2015.  Reactivity of [U(CH2SiMe2NSiMe3)(NR2)2] (R = SiMe3) with elemental chalcogens: towards a better understanding of chalcogen atom transfer in the actinides. New J Chem. 39:7563-7566.
Kent GT, Staun SL, Wu G, Hayton TW.  2020.  Reactivity of [Ce(NR2)3] (R = SiMe3) with Prospective Carbon Atom Transfer Reagents. Organometallics. 39:2375–2382.
Hartmann NJ, Wu G, Hayton TW.  2016.  Reactivity of a Nickel Sulfide with Carbon Monoxide and Nitric Oxide. Journal of the American Chemical Society. 138:12352-12355.
Lewis RA, Smiles DE, Darmon JM, S. Stieber CE, Wu G, Hayton TW.  2013.  Reactivity and Mössbauer spectroscopic characterization of an Fe(IV) ketimide complex and reinvestigation of an Fe(IV) norbornyl complex. Inorg Chem. 52(14):8218-27.
Fortier S, Kaltsoyannis N, Wu G, Hayton TW.  2011.  Probing the reactivity and electronic structure of a uranium(V) terminal oxo complex. J Am Chem Soc. 133(36):14224-7.
Seaman LA, Wu G, Edelstein N, Lukens WW, Magnani N, Hayton TW.  2012.  Probing the 5f orbital contribution to the bonding in a U(V) ketimide complex. J Am Chem Soc. 134(10):4931-40.
Pedrick EA, Wu G, Hayton TW.  2015.  Oxo Ligand Substitution in a Cationic Uranyl Complex: Synergistic Interaction of an Electrophile and a Reductant. Inorg Chem. 54(14):7038-44.
Brown JL, Wu G, Hayton TW.  2010.  Oxo ligand silylation in a uranyl β-ketoiminate complex. J Am Chem Soc. 132(21):7248-9.
Assefa MK, Pedrick EA, Wakefield ME, Wu G, Hayton TW.  2018.  Oxidation of the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene upon Ligation to the Uranyl Ion. Inorganic Chemistry. 57(14):8317–8324.
Nguyen T-AD, Wright AM, Page JS, Wu G, Hayton TW.  2014.  Oxidation of alcohols and activated alkanes with Lewis acid-activated TEMPO. Inorg Chem. 53(21):11377-87.
Cook AW, Jones ZR, Wu G, Scott SL, Hayton TW.  2018.  An Organometallic Cu20 Nanocluster: Synthesis, Characterization, Immobilization on Silica, and “Click” Chemistry. J. Am. Chem. Soc.. 140:394-400.
Wright AM, Zaman HT, Wu G, Hayton TW.  2013.  Nitric oxide release from a nickel nitrosyl complex induced by one-electron oxidation. Inorg Chem. 52(6):3207-16.
Hayton TW, Wu G.  2008.  Mixed-ligand uranyl(V) β-diketiminate/β-diketonate complexes: synthesis and characterization. Inorg Chem. 47(16):7415-23.
Wright AM, Zaman HT, Wu G, Hayton TW.  2014.  Mechanistic insights into the formation of N2O by a nickel nitrosyl complex. Inorg Chem. 53(6):3108-16.
Nguyen T-AD, Jones ZR, Leto DF, Wu G, Scott SL, Hayton TW.  2016.  Ligand Exchange-Induced Growth of an Atomically Precise Cu29 Nanocluster from a Smaller Cluster. Chemistry of Materials. 28:8385–8390.
Wright AM, Wu G, Hayton TW.  2011.  Late-metal nitrosyl cations: synthesis and reactivity of [Ni(NO)(MeNO2)3][PF6]. Inorg Chem. 50(22):11746-53.
Cook AW, Hrobárik P, Damon PL, Wu G, Hayton TW.  2020.  A Ketimide-Stabilized Palladium Nanocluster with a Hexagonal Aromatic Pd7 Core. Inorg. Chem.. 59:1471-1480.
Seaman LA, Schnaars DD, Wu G, Hayton TW.  2010.  Isolation of a uranyl amide by "ate" complex formation. Dalton Trans. 39(29):6635-7.
Seaman LA, Walensky JR, Wu G, Hayton TW.  2013.  In pursuit of homoleptic actinide alkyl complexes. Inorg Chem. 52(7):3556-64.
Fortier S, Melot BC, Wu G, Hayton TW.  2009.  Homoleptic uranium(IV) alkyl complexes: synthesis and characterization. J Am Chem Soc. 131(42):15512-21.
Fortier S, Walensky JR, Wu G, Hayton TW.  2011.  High-valent uranium alkyls: evidence for the formation of UVI(CH2SiMe3)6. J Am Chem Soc. 133(30):11732-43.
Touchton AJ, Wu G, Hayton TW.  2020.  Generation of a Ni3 Phosphinidene Cluster from the Ni(0) Synthon, Ni(η3-CPh3)2. Organometallics. 39:1360–1365.
Wright AM, Wu G, Hayton TW.  2012.  Formation of N2O from a nickel nitrosyl: isolation of the cis-[N2O2]2- intermediate. J Am Chem Soc. 134(24):9930-3.
Damon PL, Wu G, Kaltsoyannis N, Hayton TW.  2016.  Formation of a Ce(IV) Oxo Complex via Inner Sphere Nitrate Reduction. Journal of the American Chemical Society. 138:12743-12746.
Brown JL, Mokhtarzadeh CC, Lever JM, Wu G, Hayton TW.  2011.  Facile reduction of a uranyl(VI) β-ketoiminate complex to U(IV) upon oxo silylation. Inorg Chem. 50(11):5105-12.
Hayton TW, Wu G.  2009.  Exploring the effects of reduction or Lewis acid coordination on the U=O bond of the uranyl moiety. Inorg Chem. 48(7):3065-72.
Staun SL, Stevens LM, Smiles DE, Goodwin CAP, Billow BS, Scott BL, Wu G, Tondreau AM, Gaunt AJ, Hayton TW.  2021.  Expanding the Nonaqueous Chemistry of Neptunium: Synthesis and Structural Characterization of [Np(NR2)3Cl], [Np(NR2)3Cl]−, and [NpN(R)(SiMe2CH2)2(NR2)]− (R = SiMe3). Inorganic Chemistry. ASAP Article
Wright AM, Page JS, Scepaniak JJ, Wu G, Hayton TW.  2013.  Divergent Reactivity of TEMPO with MBr3 (M = B, Al). Eur J Inorg Chem. 2013:3817–3820.
Schnaars DD, Batista ER, Gaunt AJ, Hayton TW, May I, Reilly SD, Scott BL, Wu G.  2011.  Differences in actinide metal-ligand orbital interactions: comparison of U(IV) and Pu(IV) β-ketoiminate N,O donor complexes. Chem Commun (Camb). 47(27):7647-9.
Nguyen T-AD, Jones ZR, Goldsmith BR, Buratto WR, Wu G, Scott SL, Hayton TW.  2015.  A Cu25 Nanocluster with Partial Cu(0) Character. J Am Chem Soc. 137(41):13319-24.
Wright AM, Irving BJ, Wu G, Meijer AJHM, Hayton TW.  2015.  A copper(I)-arene complex with an unsupported η6 interaction. Angew Chem Int Ed Engl. 54(10):3088-91.
Kent GT, Murillo J, Wu G, Fortier S, Hayton TW.  2020.  Coordination of Uranyl to the Redox-Active Calix[4]pyrrole Ligand. Inorganic Chemistry. 59:8629–8634.
Schettini MF, Wu G, Hayton TW.  2009.  Coordination of N-donor ligands to a uranyl(V) β-diketiminate complex. Inorg Chem. 48(24):11799-808.
Scepaniak JJ, Wu G, Hayton TW.  2012.  Complexes of Cu(I) supported by a tris(ketimine) tripod. Dalton Trans. 41(26):7859-61.
Brown JL, Fortier S, Lewis RA, Wu G, Hayton TW.  2012.  A complete family of terminal uranium chalcogenides, [U(E)(N{SiMe3}2)3]- (E = O, S, Se, Te). J Am Chem Soc. 134(37):15468-75.
Seaman LA, Fortier S, Wu G, Hayton TW.  2011.  Comparison of the redox chemistry of primary and secondary amides of U(IV): isolation of a U(VI) bis(imido) complex or a homoleptic U(VI) amido complex. Inorg Chem. 50(2):636-46.
Seaman LA, Pedrick EA, Tsuchiya T, Wu G, Jakubikova E, Hayton TW.  2013.  Comparison of the reactivity of 2-Li-C6H4CH2NMe2 with MCl4 (M=Th, U): isolation of a thorium aryl complex or a uranium benzyne complex. Angew Chem Int Ed Engl. 52(40):10589-92.
Brown JL, Wu G, Hayton TW.  2013.  Chalcogen Atom Transfer to Uranium(III): Synthesis and Characterization of [(R2N)3U]2(μ-E) and [(R2N)3U]2(μ-η22-S2) (R = SiMe3; E = S, Se, Te). Organometallics. 32:1193-1198.
Schnaars DD, Wu G, Hayton TW.  2011.  Borane-mediated silylation of a metal-oxo ligand. Inorg Chem. 50(11):4695-7.
Schnaars DD, Gaunt AJ, Hayton TW, Jones MB, Kirker I, Kaltsoyannis N, May I, Reilly SD, Scott BL, Wu G.  2012.  Bonding trends traversing the tetravalent actinide series: synthesis, structural, and computational analysis of AnIV(Aracnac)4 complexes (An = Th, U, Np, Pu). Inorg Chem. 51(15):8557-66.
Hartmann NJ, Wu G, Hayton T.W.  2016.  Activation of CS2 by a "masked" terminal nickel sulfide. Dalton Trans. 45:14508-14510.