Publications
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2021. Reductive Coupling of Xylyl Isocyanide Mediated by Low-Valent Uranium. Organometallics. 40:2934–2938.
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2020. Coordination of Uranyl to the Redox-Active Calix[4]pyrrole Ligand. Inorganic Chemistry. 59:8629–8634.
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2013. Quantifying the σ and π interactions between U(V) f orbitals and halide, alkyl, alkoxide, amide and ketimide ligands. J Am Chem Soc. 135(29):10742-54.
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2013. A rare uranyl(VI)-alkyl ate complex [Li(DME)1.5]2[UO2(CH2SiMe3)4] and its comparison with a homoleptic uranium(VI)-hexaalkyl. Angew Chem Int Ed Engl. 52(11):3259-63.
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2013. Synthesis and spectroscopic and computational characterization of the chalcogenido-substituted analogues of the uranyl ion, [OUE]2+ (E = S, Se). J Am Chem Soc. 135(14):5352-5.
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2012. A complete family of terminal uranium chalcogenides, [U(E)(N{SiMe3}2)3]- (E = O, S, Se, Te). J Am Chem Soc. 134(37):15468-75.
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2012. Synthesis, molecular and electronic structure of UV(O)[N(SiMe3)2]3. Inorg Chem. 51(3):1625-33.
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2011. Comparison of the redox chemistry of primary and secondary amides of U(IV): isolation of a U(VI) bis(imido) complex or a homoleptic U(VI) amido complex. Inorg Chem. 50(2):636-46.
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2011. High-valent uranium alkyls: evidence for the formation of UVI(CH2SiMe3)6. J Am Chem Soc. 133(30):11732-43.
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2011. Probing the reactivity and electronic structure of a uranium(V) terminal oxo complex. J Am Chem Soc. 133(36):14224-7.
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2011. Synthesis of a phosphorano-stabilized U(IV)-carbene via one-electron oxidation of a U(III)-ylide adduct. J Am Chem Soc. 133(18):6894-7.
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2010. Oxo ligand functionalization in the uranyl ion (UO22+). Coord Chem Rev. 254:197-214.
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2010. Synthesis of a nitrido-substituted analogue of the uranyl ion, [N=U=O]+. J Am Chem Soc. 132(20):6888-9.
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2010. U(IV) and U(V) azide complexes supported by amide or aryloxide ligands. Dalton Trans. (2):352-4.
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2009. Homoleptic uranium(IV) alkyl complexes: synthesis and characterization. J Am Chem Soc. 131(42):15512-21.
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2009. Synthesis and redox chemistry of high-valent uranium aryloxides. Inorg Chem. 48(7):3000-11.
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2008. Synthesis and characterization of three homoleptic alkoxides of uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UVtBu)6], and UVI(OtBu)6. Inorg Chem. 47(11):4752-61.