Publications

Found results
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Cook AW, Hayton TW.  2018.  Case Studies in Nanocluster Synthesis and Characterization: Challenges and Opportunities. Accounts of Chemical Research. 51:2456-2464.
Brown JL, Wu G, Hayton TW.  2013.  Chalcogen Atom Transfer to Uranium(III): Synthesis and Characterization of [(R2N)3U]2(μ-E) and [(R2N)3U]2(μ-η22-S2) (R = SiMe3; E = S, Se, Te). Organometallics. 32:1193-1198.
Seaman LA, Pedrick EA, Tsuchiya T, Wu G, Jakubikova E, Hayton TW.  2013.  Comparison of the reactivity of 2-Li-C6H4CH2NMe2 with MCl4 (M=Th, U): isolation of a thorium aryl complex or a uranium benzyne complex. Angew Chem Int Ed Engl. 52(40):10589-92.
Seaman LA, Fortier S, Wu G, Hayton TW.  2011.  Comparison of the redox chemistry of primary and secondary amides of U(IV): isolation of a U(VI) bis(imido) complex or a homoleptic U(VI) amido complex. Inorg Chem. 50(2):636-46.
Brown JL, Fortier S, Lewis RA, Wu G, Hayton TW.  2012.  A complete family of terminal uranium chalcogenides, [U(E)(N{SiMe3}2)3]- (E = O, S, Se, Te). J Am Chem Soc. 134(37):15468-75.
Scepaniak JJ, Wu G, Hayton TW.  2012.  Complexes of Cu(I) supported by a tris(ketimine) tripod. Dalton Trans. 41(26):7859-61.
Hayton TW, Legzdins P, W. Sharp B.  2002.  Coordination and organometallic chemistry of metal-NO complexes. Chem Rev. 102(4):935-92.
Smiles DE, Hayton TW.  2015.  Coordination chemistry of the actinide elements. McGraw-Hill Yearbook of Science and Technology.
Schettini MF, Wu G, Hayton TW.  2009.  Coordination of N-donor ligands to a uranyl(V) β-diketiminate complex. Inorg Chem. 48(24):11799-808.
Kent GT, Murillo J, Wu G, Fortier S, Hayton TW.  2020.  Coordination of Uranyl to the Redox-Active Calix[4]pyrrole Ligand. Inorganic Chemistry. 59:8629–8634.
Wright AM, Irving BJ, Wu G, Meijer AJHM, Hayton TW.  2015.  A copper(I)-arene complex with an unsupported η6 interaction. Angew Chem Int Ed Engl. 54(10):3088-91.
Hayton TW, Boncella JM, Scott BL, Abboud KA, Mills RC.  2005.  Coupling of an aldehyde or ketone to pyridine mediated by a tungsten imido complex. Inorg Chem. 44(25):9506-17.
Nguyen T-AD, Jones ZR, Goldsmith BR, Buratto WR, Wu G, Scott SL, Hayton TW.  2015.  A Cu25 Nanocluster with Partial Cu(0) Character. J Am Chem Soc. 137(41):13319-24.
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Gladfelder J, Ghosh S, Podunavac M, Cook AW, Ma Y, Woltornist RA, Keresztes I, Hayton TW, Collum DB, Zakarian A.  2019.  Enantioselective Alkylation of 2-Alkyl Pyridines Controlled by Organolithium Aggregation. Journal of the American Chemical Society. 141:15024-15028.
Ma Y, Stivala CE, Wright AM, Hayton TW, Liang J, Keresztes I, Lobkovsky E, Collum DB, Zakarian A.  2013.  Enediolate–Dilithium Amide Mixed Aggregates in the Enantioselective Alkylation of Arylacetic Acids: Structural Studies and a Stereochemical Model. J Am Chem Soc. 135:16853-16864.
Gaunt AJ, Reilly SD, Hayton TW, Scott BL, Neu MP.  2007.  An entry route into non-aqueous plutonyl coordination chemistry. Chem Commun (Camb). (16):1659-61.
Hayton TW, Legzdins P, Rettig SJ.  2002.  5-cyclopentadienyl)(p-fluorophenoxo)(nitrosyl)(trimethylsilylmethyl)molybdenum(II). Acta Crystallogr C. 58(Pt 2):m68-9.
Nguyen TH, Paul EL, Lukens WW, Hayton TW.  2023.  Evaluating f-Orbital Participation in the UV═E Multiple Bonds of [U(E)(NR2)3] (E = O, NSiMe3, NAd; R = SiMe3). Inorganic Chemistry. 62:6447-6457.
Hayton TW, Boncella JM, Scott BL, Batista ER.  2006.  Exchange of an imido ligand in bis(imido) complexes of uranium. J Am Chem Soc. 128(39):12622-3.
Staun SL, Stevens LM, Smiles DE, Goodwin CAP, Billow BS, Scott BL, Wu G, Tondreau AM, Gaunt AJ, Hayton TW.  2021.  Expanding the Nonaqueous Chemistry of Neptunium: Synthesis and Structural Characterization of [Np(NR2)3Cl], [Np(NR2)3Cl]−, and [NpN(R)(SiMe2CH2)2(NR2)]− (R = SiMe3). Inorganic Chemistry. 60:2740–2748.
Hertler PR, Yu X, Brower JD, Nguyen T-AD, Wu G, Autschbach J, Hayton TW.  2024.  Exploring Spin-Orbit Effects in a [Cu6Tl]+ Nanocluster Featuring an Uncommon Tl-H Interaction. Chemistry – A European Journal. 30:e202400390.
Hayton TW, Wu G.  2009.  Exploring the effects of reduction or Lewis acid coordination on the U=O bond of the uranyl moiety. Inorg Chem. 48(7):3065-72.
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Seaman LA, Hrobárik P, Schettini MF, Fortier S, Kaupp M, Hayton TW.  2013.  A rare uranyl(VI)-alkyl ate complex [Li(DME)1.5]2[UO2(CH2SiMe3)4] and its comparison with a homoleptic uranium(VI)-hexaalkyl. Angew Chem Int Ed Engl. 52(11):3259-63.
Lewis RA, Smiles DE, Darmon JM, S. Stieber CE, Wu G, Hayton TW.  2013.  Reactivity and Mössbauer spectroscopic characterization of an Fe(IV) ketimide complex and reinvestigation of an Fe(IV) norbornyl complex. Inorg Chem. 52(14):8218-27.
Hartmann NJ, Wu G, Hayton TW.  2016.  Reactivity of a Nickel Sulfide with Carbon Monoxide and Nitric Oxide. Journal of the American Chemical Society. 138:12352-12355.
Kent GT, Staun SL, Wu G, Hayton TW.  2020.  Reactivity of [Ce(NR2)3] (R = SiMe3) with Prospective Carbon Atom Transfer Reagents. Organometallics. 39:2375–2382.
Hayton TW, Patrick BO, Legzdins P.  2004.  Reactivity of (trimpsi)V(NO)X2 Complexes (X = Cl, Br, I; trimpsi = tBuSi(CH2PMe2)3). Synthesis of the First Group 5 Alkyl Nitrosyls. Organometallics. 23:657-664.
Smiles DE, Wu G, Hayton TW.  2015.  Reactivity of [U(CH2SiMe2NSiMe3)(NR2)2] (R = SiMe3) with elemental chalcogens: towards a better understanding of chalcogen atom transfer in the actinides. New J Chem. 39:7563-7566.
Schnaars DD, Wu G, Hayton TW.  2008.  Reactivity of UH3 with mild oxidants. Dalton Trans. (44):6121-6.
Schnaars DD, Wu G, Hayton TW.  2009.  Reactivity of UI4(OEt2)2 with phenols: probing the chemistry of the U-I bond. Dalton Trans. (19):3681-7.
Hayton TW.  2013.  Recent developments in actinide-ligand multiple bonding. Chem Commun (Camb). 49(29):2956-73.
Schnaars DD, Wu G, Hayton TW.  2009.  Reduction of pentavalent uranyl to U(IV) facilitated by oxo functionalization. J Am Chem Soc. 131(48):17532-3.
Staun SL, Kent GT, Gomez-Torres A, Wu G, Fortier S, Hayton TW.  2021.  Reductive Coupling of Xylyl Isocyanide Mediated by Low-Valent Uranium. Organometallics. 40:2934–2938.
Pedrick EA, Wu G, Kaltsoyannis N, Hayton TW.  2014.  Reductive silylation of a uranyl dibenzoylmethanate complex: an example of controlled uranyl oxo ligand cleavage. Chem Sci. 5:3204-3213.
Pedrick EA, Wu G, Hayton TW.  2014.  Reductive silylation of the uranyl ion with Ph3SiOTf. Inorg Chem. 53(23):12237-9.
Cook AW, Wu G, Hayton TW.  2018.  A Re-examination of the Synthesis of Monolayer-Protected Cox(SCH2CH2Ph)m Nanoclusters: Unexpected Formation of a Thiolate-Protected Co(II) T3 Supertetrahedron. Inorganic Chemistry. 57(14):8189–8194.
Smiles DE, Wu G, Hayton TW.  2014.  Reversible chalcogen-atom transfer to a terminal uranium sulfide. Inorg Chem. 53(24):12683-5.
Ordoñez O, Kent GT, Schuerlein MA, Wu G, Hayton TW.  2023.  Ring-Opening in the Actinide Cyclopropyl Complexes [Cp3U(2,2-Diphenylcyclopropyl)]n (n = 0, 1). Organometallics. 42:2347–2352.
Kent G, Yu X, Wu G, Autschbach J, Hayton TW.  2022.  Ring-opening of a Thorium Cyclopropenyl Complex Generates a Transient Thorium-bound Carbene. Chem. Commun.. 58:6805-6808.
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Keener M, Mattejat M, Zheng S-L, Wu G, Hayton TW, Ménard G.  2022.  Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes. Chem. Sci.. 13:3369-3374.
Schnaars DD, Wu G, Hayton TW.  2011.  Silylation of the uranyl ion using B(C6F5)3-activated Et3SiH. Inorg Chem. 50(19):9642-9.
Hayton TW, Patrick BO, Legzdins P, W. McNeil S.  2004.  The solid-state molecular structure of W(NO)3Cl3 and the nature of its W-NO bonding. Can J Chem. 82:285-292.
Lewis RA, Wu G, Hayton TW.  2011.  Stabilizing high-valent metal ions with a ketimide ligand set: synthesis of Mn(N=CtBu2)4. Inorg Chem. 50(10):4660-8.
Cinco MÁBaeza, Wu G, Telser J, Hayton TW.  2022.  Structural and Spectroscopic Characterization of a Zinc-Bound N-Oxyphthalimide Radical. Inorganic Chemistry. 61:13250–13255.
Wright AM, Wu G, Hayton TW.  2010.  Structural characterization of a copper nitrosyl complex with a {CuNO}10 configuration. J Am Chem Soc. 132(41):14336-7.
Nguyen T-AD, Cook AW, Wu G, Hayton TW.  2017.  Subnanometer-Sized Copper Clusters: A Critical Re-evaluation of the Synthesis and Characterization of Cu8(MPP)4 (HMPP = 2-Mercapto-5-n-propylpyrimidine). Inorganic Chemistry. 56:8390–8396.
Nguyen T-AD, Goldsmith BR, Zaman HT, Wu G, Peters B, Hayton TW.  2015.  Synthesis and characterization of a Cu14 hydride cluster supported by neutral donor ligands. Chem Eur J. 21(14):5341-4.
Cook AW, Hrobárik P, Damon PL, Najera D, Horváth B, Wu G, Hayton TW.  2019.  Synthesis and Characterization of a Linear, Two-Coordinate Pt(II) Ketimide Complex. Inorganic Chemistry. 58:15927-15935.
Lewis RA, Wu G, Hayton TW.  2010.  Synthesis and characterization of an iron(IV) ketimide complex. J Am Chem Soc. 132(37):12814-6.
Cook AW, Jones ZR, Wu G, Teat SJ, Scott SL, Hayton TW.  2019.  Synthesis and Characterization of “Atlas-Sphere” Copper Nanoclusters: New Insights into the Reaction of Cu2+ with Thiols. Inorganic Chemistry. 58:8739-8749.
Lewis RA, Morochnik S, Chapovetsky A, Wu G, Hayton TW.  2012.  Synthesis and characterization of [M2(N=CtBu2)5]- (M=Mn, Fe, Co): metal ketimide complexes with strong metal-metal interactions. Angew Chem Int Ed Engl. 51(51):12772-5.
Fortier S, Wu G, Hayton TW.  2008.  Synthesis and characterization of three homoleptic alkoxides of uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UVtBu)6], and UVI(OtBu)6. Inorg Chem. 47(11):4752-61.
Kent GT, Cook AW, Damon PL, Lewis RA, Wu G, Hayton TW.  2021.  Synthesis and Characterization of Two “Tied-Back” Lithium Ketimides and Isolation of a Ketimide-Bridged [Cr2]6+ Dimer with Strong Antiferromagnetic Coupling. Inorganic Chemistry. 60:4996–5004.
Ordoñez O, Yu X, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis and Characterization of Two Uranyl-Aryl “Ate” Complexes. Chemistry – A European Journal. 27:5885-5889.
Kent GT, Wu G, Hayton TW.  2019.  Synthesis and Crystallographic Characterization of the Tetravalent Actinide-DOTA Complexes [AnIV8-DOTA)(DMSO)] (An = Th, U). Inorganic Chemistry. 58:8253-8256.
Kent G, Yu X, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis and Electronic Structure Analysis of the Actinide Allenylidenes, [(NR2)3An(CCCPh2)]- (An = U, Th; R = SiMe3). Chemical Science. 12:14383-14388.
Hartmann NJ, Wu G., Hayton TW.  2018.  Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N2O reduction. Chem. Sci.. 9(31):6580-6588.
Pedrick EA, Seaman LA, Scott JC, Griego L, Wu G., Hayton TW.  2016.  Synthesis and Reactivity of a U(IV) Dibenzyne Complex. Organometallics. 35:494-502.
Schettini MF, Wu G, Hayton TW.  2012.  Synthesis and reactivity of a uranyl-imidazolyl complex. Chem Commun (Camb). 48(10):1484-6.
Spencer LP, Gdula RL, Hayton TW, Scott BL, Boncella JM.  2008.  Synthesis and reactivity of bis(imido) uranium(VI) cyclopentadienyl complexes. Chem Commun (Camb). (40):4986-8.
Hayton TW, Boncella JM, Scott BL, Batista ER, P. Hay J.  2006.  Synthesis and reactivity of the imido analogues of the uranyl ion. J Am Chem Soc. 128(32):10549-59.
Fortier S, Wu G, Hayton TW.  2009.  Synthesis and redox chemistry of high-valent uranium aryloxides. Inorg Chem. 48(7):3000-11.
Brown JL, Fortier S, Wu G, Kaltsoyannis N, Hayton TW.  2013.  Synthesis and spectroscopic and computational characterization of the chalcogenido-substituted analogues of the uranyl ion, [OUE]2+ (E = S, Se). J Am Chem Soc. 135(14):5352-5.
Assefa MK, Sergentu D-C, Seaman LA, Wu G, Autschbach J, Hayton TW.  2019.  Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li]2[M(N═CtBuPh)6] (M = Ce, Th). Inorganic Chemistry. 58:12654-12661.
Hayton TW, Wu G.  2008.  Synthesis, characterization, and reactivity of a uranyl β-diketiminate complex. J Am Chem Soc. 130(6):2005-14.
Cook AW, Nguyen T-AD, Buratto WR, Wu G, Hayton TW.  2016.  Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)4(OAc)2] and [Cu3H(dppm)3(OAc)2]. Inorg. Chem.. 55:12435-12440.
Hayton TW, P. Daff J, Legzdins P, Rettig SJ, Patrick BO.  2002.  Synthesis, characterization, and solution redox properties of (trimpsi)M(CO)2(NO) complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3]. Inorg Chem. 41(16):4114-26.
Smiles DE, Wu G, Hayton TW.  2016.  Synthesis, Electrochemistry, and Reactivity of the Actinide Trisulfides [K(18-crown-6)][An(η3-S3)(NR2)3] (An = U, Th; R = SiMe3). Inorganic Chemistry. 55:9150-9153.
Fortier S, Brown JL, Kaltsoyannis N, Wu G, Hayton TW.  2012.  Synthesis, molecular and electronic structure of UV(O)[N(SiMe3)2]3. Inorg Chem. 51(3):1625-33.
Lewis RA, George SP, Chapovetsky A, Wu G, Figueroa JS, Hayton TW.  2013.  Synthesis of a cobalt(IV) ketimide with a squashed tetrahedral geometry. Chem Commun (Camb). 49(28):2888-90.
Hartmann NJ, Wu G, Hayton TW.  2015.  Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide. Angew Chem Int Ed Engl. 54(49):14956-9.
Hayton TW, Staun S, Lukens W, Wu G.  2021.  Synthesis of a Mixed-valent Heterobimetallic Actinide Nitride and an Analysis of its Bonding. Chemical Science. 12:15519-15527.
Fortier S, Wu G, Hayton TW.  2010.  Synthesis of a nitrido-substituted analogue of the uranyl ion, [N=U=O]+. J Am Chem Soc. 132(20):6888-9.
Fortier S, Walensky JR, Wu G, Hayton TW.  2011.  Synthesis of a phosphorano-stabilized U(IV)-carbene via one-electron oxidation of a U(III)-ylide adduct. J Am Chem Soc. 133(18):6894-7.
Assefa MK, Wu G, Hayton TW.  2017.  Synthesis of a terminal Ce(iv) oxo complex by photolysis of a Ce(iii) nitrate complex. Chem. Sci.. 8:7873-7878.
Touchton AJ, Wu G, Hayton TW.  2021.  Synthesis of Bis(trityl)iron(II) and Formation of the Iron(0)-Stabilized o,o-Isomer of Gomberg’s Dimer. Organometallics. 40:4045–4049.
Hayton TW, Boncella JM, Scott BL, Palmer PD, Batista ER, P. Hay J.  2005.  Synthesis of imido analogs of the uranyl ion. Science. 310(5756):1941-3.
Kent GT, Yu X, Pauly C, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis of Parent Acetylide and Dicarbide Complexes of Thorium and Uranium and an Examination of Their Electronic Structures. Inorganic Chemistry. 60:15413–15420.
Smiles DE, Wu G, Hayton TW.  2014.  Synthesis of terminal monochalcogenide and dichalcogenide complexes of uranium using polychalcogenides, [En]2- (E = Te, n = 2; E = Se, n = 4), as chalcogen atom transfer reagents. Inorg Chem. 53(19):10240-7.
Smiles DE, Wu G, Hayton TW.  2014.  Synthesis of uranium-ligand multiple bonds by cleavage of a trityl protecting group. J Am Chem Soc. 136(1):96-9.
Pedrick EA, Hrobárik P, Seaman LA, Wu G, Hayton TW.  2016.  Synthesis, structure and bonding of hexaphenyl thorium(iv): observation of a non-octahedral structure. Chem Commun (Camb). 52(4):689-92.
Smiles DE, Wu G, Hrobárik P, Hayton TW.  2017.  Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium. Organometallics. 36:4519–4524.
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Nguyen TH, Yu X, Kent GT, Autschbach J, Hayton TW.  2023.  U-C Bond Insertion, Ring-Opening, and C-H Activation in a Uranium Bis(diisopropylamino)cyclopropenylidene (BAC) Adduct. Organometallics. 42:1005–1012.
Fortier S, Wu G, Hayton TW.  2010.  U(IV) and U(V) azide complexes supported by amide or aryloxide ligands. Dalton Trans. (2):352-4.
Touchton AJ, Wu G, Hayton TW.  2021.  Understanding the Early Stages of Nickel Sulfide Nanocluster Growth: Isolation of Ni3, Ni4, Ni5, and Ni8 Intermediates. Small. 17:2003133.
Hayton TW.  2018.  Understanding the origins of Oyl-U-Oyl bending in the uranyl (UO22+) ion. Dalton Trans.. 47:1003-1009.
Wright AM, Hayton TW.  2015.  Understanding the role of hyponitrite in nitric oxide reduction. Inorg Chem. 54(19):9330-41.
Hayton TW.  2013.  Uranium chemistry: an actinide milestone. Nat Chem. 5(6):451-2.
Pedrick EA, Assefa MK, Wakefield ME, Wu G, Hayton TW.  2017.  Uranyl Coordination by the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene. Inorganic Chemistry. 56(11):6638–6644.
Assefa MK, Wu G, Hayton TW.  2020.  Uranyl oxo silylation promoted by silsesquioxane coordination. Journal of the American Chemical Society. 142:8738–8747.
Staun SL, Sergentu D-C, Wu G, Autschbach J, Hayton TW.  2019.  Use of 15N NMR spectroscopy to probe covalency in a thorium nitride. Chem. Sci.. 10:6431-6436.
Smiles DE, Wu G, Hrobárik P, Hayton TW.  2016.  Use of 77Se and 125Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(En){N(SiMe3)2}3]- (E = Se, Te; n = 1, 2) and Their Oxo-Uranium(VI) Congeners. J Am Chem Soc. 138(3):814-25.