Publications

Found results
Author Title Type [ Year(Asc)]
Filters: Author is Smiles, Danil E.  [Clear All Filters]
2021
Staun SL, Stevens LM, Smiles DE, Goodwin CAP, Billow BS, Scott BL, Wu G, Tondreau AM, Gaunt AJ, Hayton TW.  2021.  Expanding the Nonaqueous Chemistry of Neptunium: Synthesis and Structural Characterization of [Np(NR2)3Cl], [Np(NR2)3Cl]−, and [NpN(R)(SiMe2CH2)2(NR2)]− (R = SiMe3). Inorganic Chemistry. 60:2740–2748.
2017
Smiles DE, Wu G, Hrobárik P, Hayton TW.  2017.  Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium. Organometallics. 36:4519–4524.
2016
Smiles DE, Wu G, Hayton TW.  2016.  Synthesis, Electrochemistry, and Reactivity of the Actinide Trisulfides [K(18-crown-6)][An(η3-S3)(NR2)3] (An = U, Th; R = SiMe3). Inorganic Chemistry. 55:9150-9153.
Smiles DE, Wu G, Hrobárik P, Hayton TW.  2016.  Use of 77Se and 125Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(En){N(SiMe3)2}3]- (E = Se, Te; n = 1, 2) and Their Oxo-Uranium(VI) Congeners. J Am Chem Soc. 138(3):814-25.
2015
Smiles DE, Hayton TW.  2015.  Coordination chemistry of the actinide elements. McGraw-Hill Yearbook of Science and Technology.
Smiles DE, Wu G, Hayton TW.  2015.  Reactivity of [U(CH2SiMe2NSiMe3)(NR2)2] (R = SiMe3) with elemental chalcogens: towards a better understanding of chalcogen atom transfer in the actinides. New J Chem. 39:7563-7566.
Smiles DE, Wu G, Kaltsoyannis N, Hayton TW.  2015.  Thorium-ligand multiple bonds via reductive deprotection of a trityl group. Chem Sci. 6:3891-3899.
2014
Smiles DE, Wu G, Hayton TW.  2014.  Reversible chalcogen-atom transfer to a terminal uranium sulfide. Inorg Chem. 53(24):12683-5.
Smiles DE, Wu G, Hayton TW.  2014.  Synthesis of terminal monochalcogenide and dichalcogenide complexes of uranium using polychalcogenides, [En]2- (E = Te, n = 2; E = Se, n = 4), as chalcogen atom transfer reagents. Inorg Chem. 53(19):10240-7.
Smiles DE, Wu G, Hayton TW.  2014.  Synthesis of uranium-ligand multiple bonds by cleavage of a trityl protecting group. J Am Chem Soc. 136(1):96-9.
2013
Lewis RA, Smiles DE, Darmon JM, S. Stieber CE, Wu G, Hayton TW.  2013.  Reactivity and Mössbauer spectroscopic characterization of an Fe(IV) ketimide complex and reinvestigation of an Fe(IV) norbornyl complex. Inorg Chem. 52(14):8218-27.