Publications

Found results
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Book Chapter
Hayton TW.  2023.  Atomically Precise Nanoclusters of Iron, Cobalt, and Nickel: Why are They So Rare? Atomically Precise Nanochemistry.
Smiles DE, Hayton TW.  2015.  Coordination chemistry of the actinide elements. McGraw-Hill Yearbook of Science and Technology.
Hayton TW.  2021.  Hydride, Alkyl, Aryl, Acetylide, Carbonyl, and Cyanide Complexes of the Actinides. Comprehensive Organometallic Chemistry IV.
Hayton TW, Kaltsoyannis N.  2018.  Organometallic Actinide Complexes with Novel Oxidation States and Ligand Types. Experimental and Theoretical Approaches to Actinide Chemistry. :181–236.
Pamplin CB, Hayton TW, Legzdins P.  2006.  Tungsten: Organometallic Chemistry. Encyclopedia of Inorganic Chemistry.
Journal Article
Ordoñez O, Yu X, Schuerlein MA, Wu G, Autschbach J, Hayton TW.  2024.  An Actinide Complex with a Nucleophilic Allenylidene Ligand. Journal of the American Chemical Society. 146:28306–28319.
Hartmann NJ, Wu G, Hayton T.W.  2016.  Activation of CS2 by a "masked" terminal nickel sulfide. Dalton Trans. 45:14508-14510.
Ordoñez O, Yu X, Wu G, Autschbach J, Hayton TW.  2022.  Assessing the 4f Orbital Participation in the Ln–C Bonds of [Li(THF)4][Ln(C6Cl5)4] (Ln = La, Ce). Inorganic Chemistry. 61:15138–15143.
Schnaars DD, Gaunt AJ, Hayton TW, Jones MB, Kirker I, Kaltsoyannis N, May I, Reilly SD, Scott BL, Wu G.  2012.  Bonding trends traversing the tetravalent actinide series: synthesis, structural, and computational analysis of AnIV(Aracnac)4 complexes (An = Th, U, Np, Pu). Inorg Chem. 51(15):8557-66.
Schnaars DD, Wu G, Hayton TW.  2011.  Borane-mediated silylation of a metal-oxo ligand. Inorg Chem. 50(11):4695-7.
Cook AW, Hayton TW.  2018.  Case Studies in Nanocluster Synthesis and Characterization: Challenges and Opportunities. Accounts of Chemical Research. 51:2456-2464.
Brown JL, Wu G, Hayton TW.  2013.  Chalcogen Atom Transfer to Uranium(III): Synthesis and Characterization of [(R2N)3U]2(μ-E) and [(R2N)3U]2(μ-η22-S2) (R = SiMe3; E = S, Se, Te). Organometallics. 32:1193-1198.
Seaman LA, Pedrick EA, Tsuchiya T, Wu G, Jakubikova E, Hayton TW.  2013.  Comparison of the reactivity of 2-Li-C6H4CH2NMe2 with MCl4 (M=Th, U): isolation of a thorium aryl complex or a uranium benzyne complex. Angew Chem Int Ed Engl. 52(40):10589-92.
Seaman LA, Fortier S, Wu G, Hayton TW.  2011.  Comparison of the redox chemistry of primary and secondary amides of U(IV): isolation of a U(VI) bis(imido) complex or a homoleptic U(VI) amido complex. Inorg Chem. 50(2):636-46.
Brown JL, Fortier S, Lewis RA, Wu G, Hayton TW.  2012.  A complete family of terminal uranium chalcogenides, [U(E)(N{SiMe3}2)3]- (E = O, S, Se, Te). J Am Chem Soc. 134(37):15468-75.
Scepaniak JJ, Wu G, Hayton TW.  2012.  Complexes of Cu(I) supported by a tris(ketimine) tripod. Dalton Trans. 41(26):7859-61.
Hayton TW, Legzdins P, W. Sharp B.  2002.  Coordination and organometallic chemistry of metal-NO complexes. Chem Rev. 102(4):935-92.
Schettini MF, Wu G, Hayton TW.  2009.  Coordination of N-donor ligands to a uranyl(V) β-diketiminate complex. Inorg Chem. 48(24):11799-808.
Kent GT, Murillo J, Wu G, Fortier S, Hayton TW.  2020.  Coordination of Uranyl to the Redox-Active Calix[4]pyrrole Ligand. Inorganic Chemistry. 59:8629–8634.
Wright AM, Irving BJ, Wu G, Meijer AJHM, Hayton TW.  2015.  A copper(I)-arene complex with an unsupported η6 interaction. Angew Chem Int Ed Engl. 54(10):3088-91.
Hayton TW, Boncella JM, Scott BL, Abboud KA, Mills RC.  2005.  Coupling of an aldehyde or ketone to pyridine mediated by a tungsten imido complex. Inorg Chem. 44(25):9506-17.
Nguyen TH, Ausman SF, MacGregor F, Wu G, Fortier S, Hayton TW.  2024.  The Curious Case of [AnH(NR2)3] (An = Th, U; R = SiMe3): Two Monomeric Actinide Hydrides Revisited. Organometallics. ASAP Article
Nguyen T-AD, Jones ZR, Goldsmith BR, Buratto WR, Wu G, Scott SL, Hayton TW.  2015.  A Cu25 Nanocluster with Partial Cu(0) Character. J Am Chem Soc. 137(41):13319-24.
Schnaars DD, Batista ER, Gaunt AJ, Hayton TW, May I, Reilly SD, Scott BL, Wu G.  2011.  Differences in actinide metal-ligand orbital interactions: comparison of U(IV) and Pu(IV) β-ketoiminate N,O donor complexes. Chem Commun (Camb). 47(27):7647-9.
Hayton TW, Legzdins P, Patrick BO.  2002.  Differing reactivities of (trimpsi)M(CO)2(NO) complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3] with halogens and halogen sources. Inorg Chem. 41(21):5388-96.
Nguyen TH, Pauly C, Kent GT, Wu G, Hayton TW.  2023.  Dimerization and ring-opening in bis(diisopropylamino)cyclopropenylidene (BAC) mediated by [U(NR2)3(CCPh)] (R = SiMe3). Dalton Transactions. 52:13868-13871.
Hayton TW, Legzdins P, Rettig SJ.  2002.  Di-μ-methoxy-bis[(η5-cyclopentadienyl)(nitrosyl-κ-N)(trimethylsilylmethyl)molybdenum(II)]. Acta Crystallogr C. 58(Pt 7):m377-8.
Jilek RE, Spencer LP, Lewis RA, Scott BL, Hayton TW, Boncella JM.  2012.  A direct route to bis(imido)uranium(V) halides via metathesis of uranium tetrachloride. J Am Chem Soc. 134(24):9876-8.
Wright AM, Page JS, Scepaniak JJ, Wu G, Hayton TW.  2013.  Divergent Reactivity of TEMPO with MBr3 (M = B, Al). Eur J Inorg Chem. 2013:3817–3820.
Gladfelder J, Ghosh S, Podunavac M, Cook AW, Ma Y, Woltornist RA, Keresztes I, Hayton TW, Collum DB, Zakarian A.  2019.  Enantioselective Alkylation of 2-Alkyl Pyridines Controlled by Organolithium Aggregation. Journal of the American Chemical Society. 141:15024-15028.
Ma Y, Stivala CE, Wright AM, Hayton TW, Liang J, Keresztes I, Lobkovsky E, Collum DB, Zakarian A.  2013.  Enediolate–Dilithium Amide Mixed Aggregates in the Enantioselective Alkylation of Arylacetic Acids: Structural Studies and a Stereochemical Model. J Am Chem Soc. 135:16853-16864.
Gaunt AJ, Reilly SD, Hayton TW, Scott BL, Neu MP.  2007.  An entry route into non-aqueous plutonyl coordination chemistry. Chem Commun (Camb). (16):1659-61.
Hayton TW, Legzdins P, Rettig SJ.  2002.  5-cyclopentadienyl)(p-fluorophenoxo)(nitrosyl)(trimethylsilylmethyl)molybdenum(II). Acta Crystallogr C. 58(Pt 2):m68-9.
Nguyen TH, Paul EL, Lukens WW, Hayton TW.  2023.  Evaluating f-Orbital Participation in the UV═E Multiple Bonds of [U(E)(NR2)3] (E = O, NSiMe3, NAd; R = SiMe3). Inorganic Chemistry. 62:6447-6457.
Hayton TW, Boncella JM, Scott BL, Batista ER.  2006.  Exchange of an imido ligand in bis(imido) complexes of uranium. J Am Chem Soc. 128(39):12622-3.
Staun SL, Stevens LM, Smiles DE, Goodwin CAP, Billow BS, Scott BL, Wu G, Tondreau AM, Gaunt AJ, Hayton TW.  2021.  Expanding the Nonaqueous Chemistry of Neptunium: Synthesis and Structural Characterization of [Np(NR2)3Cl], [Np(NR2)3Cl]−, and [NpN(R)(SiMe2CH2)2(NR2)]− (R = SiMe3). Inorganic Chemistry. 60:2740–2748.
Hertler PR, Yu X, Brower JD, Nguyen T-AD, Wu G, Autschbach J, Hayton TW.  2024.  Exploring Spin-Orbit Effects in a [Cu6Tl]+ Nanocluster Featuring an Uncommon Tl-H Interaction. Chemistry – A European Journal. 30:e202400390.
Hayton TW, Wu G.  2009.  Exploring the effects of reduction or Lewis acid coordination on the U=O bond of the uranyl moiety. Inorg Chem. 48(7):3065-72.
Brown JL, Mokhtarzadeh CC, Lever JM, Wu G, Hayton TW.  2011.  Facile reduction of a uranyl(VI) β-ketoiminate complex to U(IV) upon oxo silylation. Inorg Chem. 50(11):5105-12.
Damon PL, Wu G, Kaltsoyannis N, Hayton TW.  2016.  Formation of a Ce(IV) Oxo Complex via Inner Sphere Nitrate Reduction. Journal of the American Chemical Society. 138:12743-12746.
Wright AM, Wu G, Hayton TW.  2012.  Formation of N2O from a nickel nitrosyl: isolation of the cis-[N2O2]2- intermediate. J Am Chem Soc. 134(24):9930-3.
Touchton AJ, Wu G, Hayton TW.  2020.  Generation of a Ni3 Phosphinidene Cluster from the Ni(0) Synthon, Ni(η3-CPh3)2. Organometallics. 39:1360–1365.
Fortier S, Walensky JR, Wu G, Hayton TW.  2011.  High-valent uranium alkyls: evidence for the formation of UVI(CH2SiMe3)6. J Am Chem Soc. 133(30):11732-43.
Hertler PR, de la Vega ASauza-, Darù A, Sarkar A, Lewis RA, Wu G, Gagliardi L, Hayton TW.  2024.  A homoleptic Fe(iv) ketimide complex with a low-lying excited state. Chem. Sci.. 15:16559-16566.
Ordoñez O, Yu X, Wu G, Autschbach J, Hayton TW.  2021.  Homoleptic Perchlorophenyl "Ate" Complexes of Thorium(IV) and Uranium(IV). Inorganic Chemistry. 60:12436–12444.
Fortier S, Melot BC, Wu G, Hayton TW.  2009.  Homoleptic uranium(IV) alkyl complexes: synthesis and characterization. J Am Chem Soc. 131(42):15512-21.
Seaman LA, Walensky JR, Wu G, Hayton TW.  2013.  In pursuit of homoleptic actinide alkyl complexes. Inorg Chem. 52(7):3556-64.
Cook AW, Bocarsly JD, Lewis RA, Touchton AJ, Morochnik S, Hayton TW.  2020.  An Iron Ketimide Single-molecule Magnet [Fe4(N=CPh2)6] with Suppressed Through-barrier Relaxation. Chem. Sci.. 11:4753-4757.
Seaman LA, Schnaars DD, Wu G, Hayton TW.  2010.  Isolation of a uranyl amide by "ate" complex formation. Dalton Trans. 39(29):6635-7.
Cook AW, Hrobárik P, Damon PL, Wu G, Hayton TW.  2020.  A Ketimide-Stabilized Palladium Nanocluster with a Hexagonal Aromatic Pd7 Core. Inorg. Chem.. 59:1471-1480.
Wright AM, Wu G, Hayton TW.  2011.  Late-metal nitrosyl cations: synthesis and reactivity of [Ni(NO)(MeNO2)3][PF6]. Inorg Chem. 50(22):11746-53.
Nguyen T-AD, Jones ZR, Leto DF, Wu G, Scott SL, Hayton TW.  2016.  Ligand Exchange-Induced Growth of an Atomically Precise Cu29 Nanocluster from a Smaller Cluster. Chemistry of Materials. 28:8385–8390.
Yu K, Lu P, Jackson JJ, Nguyen T-AD, Alvarado J, Stivala CE, Ma Y, Mack KA, Hayton TW, Collum DB et al..  2017.  Lithium Enolates in the Enantioselective Construction of Tetrasubstituted Carbon Centers with Chiral Lithium Amides as Noncovalent Stereodirecting Auxiliaries. Journal of the American Chemical Society. 139:527-533.
Gaunt AJ, Reilly SD, Enriquez AE, Hayton TW, Boncella JM, Scott BL, Neu MP.  2008.  Low-valent molecular plutonium halide complexes. Inorg Chem. 47(18):8412-9.
Hertler PR, Lewis RA, Wu G, Hayton TW.  2023.  Measuring Metal–Metal Communication in a Series of Ketimide-Bridged [Fe2]6+ Complexes. Inorganic Chemistry. 62:11829–11836.
Wright AM, Zaman HT, Wu G, Hayton TW.  2014.  Mechanistic insights into the formation of N2O by a nickel nitrosyl complex. Inorg Chem. 53(6):3108-16.
Hayton TW.  2010.  Metal-ligand multiple bonding in uranium: structure and reactivity. Dalton Trans. 39(5):1145-58.
Hertler PR, Kautzsch L, Touchton AJ, Wu G, Hayton TW.  2022.  Metal–Metal-Bonded Fe4 Clusters with Slow Magnetic Relaxation. Inorganic Chemistry. 61:9997–10005.
Hayton TW, Wu G.  2008.  Mixed-ligand uranyl(V) β-diketiminate/β-diketonate complexes: synthesis and characterization. Inorg Chem. 47(16):7415-23.
Hayton TW, Patrick BO, Legzdins P.  2004.  New details concerning the reactions of nitric oxide with vanadium tetrachloride. Inorg Chem. 43(22):7227-33.
Touchton AJ, Wu G, Hayton TW.  2021.  [Ni23Se12(PEt3)13] Revisited: Isolation and Characterization of [Ni23Se12Cl3(PEt3)10]. Inorganic Chemistry. 60:17586–17592.
Touchton AJ, Wu G, Hayton TW.  2022.  [Ni30S16PEt3)11]: an open-shell nickel sulfide nanocluster with a “metal-like” core. Chem. Sci.. 13:5171-5175.
Touchton AJ, Wu G, Hayton TW.  2021.  [Ni8(CNtBu)12][Cl]: A nickel isocyanide nanocluster with a folded nanosheet structure. The Journal of Chemical Physics. 154:211102.
Wright AM, Zaman HT, Wu G, Hayton TW.  2013.  Nitric oxide release from a nickel nitrosyl complex induced by one-electron oxidation. Inorg Chem. 52(6):3207-16.
Cinco MÁBaeza, Chakraborty A, Guzman CF, Kräh S, Wu G, Hayton TW.  2023.  NO and N2O Release from the Trityl Diazeniumdiolate Complexes [M(O2N2CPh3)3] (M = Fe, Co). Inorganic Chemistry. 62:4847–4852.
Cook AW, Jones ZR, Wu G, Scott SL, Hayton TW.  2018.  An Organometallic Cu20 Nanocluster: Synthesis, Characterization, Immobilization on Silica, and “Click” Chemistry. J. Am. Chem. Soc.. 140:394-400.
Nguyen T-AD, Wright AM, Page JS, Wu G, Hayton TW.  2014.  Oxidation of alcohols and activated alkanes with Lewis acid-activated TEMPO. Inorg Chem. 53(21):11377-87.
Assefa MK, Pedrick EA, Wakefield ME, Wu G, Hayton TW.  2018.  Oxidation of the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene upon Ligation to the Uranyl Ion. Inorganic Chemistry. 57(14):8317–8324.
Fortier S, Hayton TW.  2010.  Oxo ligand functionalization in the uranyl ion (UO22+). Coord Chem Rev. 254:197-214.
Brown JL, Wu G, Hayton TW.  2010.  Oxo ligand silylation in a uranyl β-ketoiminate complex. J Am Chem Soc. 132(21):7248-9.
Pedrick EA, Wu G, Hayton TW.  2015.  Oxo Ligand Substitution in a Cationic Uranyl Complex: Synergistic Interaction of an Electrophile and a Reductant. Inorg Chem. 54(14):7038-44.
Hayton TW, Shafaat HS.  2022.  Periodic TableTalks: An Oasis of Science within a Conference Desert. Inorganic Chemistry. 61:5965-5971.
Pedrick EA, Schultz JW, Wu G, Mirica LM, Hayton TW.  2016.  Perturbation of the O–U–O Angle in Uranyl by Coordination to a 12-Membered Macrocycle. Inorganic Chemistry. 55:5693-5701.
Cinco MÁBaeza, Wu G, Hayton TW.  2023.  Photolytic C-Diazeniumdiolate Disassembly in the β-Diketiminate Complexes [MeLM(O2N2CPh3)] (M = Fe, Co, Cu). Inorganic Chemistry. 62:14064–14071.
Cinco MÁBaeza, Kräh S, Guzman CF, Wu G, Hayton TW.  2022.  Photolytic or Oxidative Fragmentation of Trityl Diazeniumdiolate (O2N2CPh3): Evidence for Both C–N and N–N Bond Cleavage. Inorganic Chemistry. 61:14924–14928.
Seaman LA, Wu G, Edelstein N, Lukens WW, Magnani N, Hayton TW.  2012.  Probing the 5f orbital contribution to the bonding in a U(V) ketimide complex. J Am Chem Soc. 134(10):4931-40.
Sergentu D-C, Kent GT, Staun SL, Yu X, Cho H, Autschbach J, Hayton TW.  2020.  Probing the Electronic Structure of a Thorium Nitride Complex by Solid-State 15N NMR Spectroscopy. Inorganic Chemistry. 59:10138–10145.
Fortier S, Kaltsoyannis N, Wu G, Hayton TW.  2011.  Probing the reactivity and electronic structure of a uranium(V) terminal oxo complex. J Am Chem Soc. 133(36):14224-7.
Cinco MÁBaeza, Hayton T.  2020.  Progress Toward the Isolation of Late Metal Terminal Sulfides. European Journal of Inorganic Chemistry. 2020:3613-3626.
Seaman LA, Pedrick EA, Wu G, Hayton TW.  2018.  Promoting oxo functionalization in the uranyl ion by ligation to ketimides. Journal of Organometallic Chemistry. 857:34-37.
Ordoñez O, Yu X, Wu G, Autschbach J, Hayton TW.  2024.  Quantifying Actinide–Carbon Bond Covalency in a Uranyl–Aryl Complex Utilizing Solution 13C NMR Spectroscopy. Inorganic Chemistry. 63:9427–9433.
Damon PL, Liss CJ, Lewis RA, Morochnik S, Szpunar DE, Telser J, Hayton TW.  2015.  Quantifying the Electron Donor and Acceptor Abilities of the Ketimide Ligands in M(N═CtBu2)4 (M = V, Nb, Ta). Inorg Chem. 54(20):10081-95.
Lukens WW, Edelstein NM, Magnani N, Hayton TW, Fortier S, Seaman LA.  2013.  Quantifying the σ and π interactions between U(V) f orbitals and halide, alkyl, alkoxide, amide and ketimide ligands. J Am Chem Soc. 135(29):10742-54.
Seaman LA, Hrobárik P, Schettini MF, Fortier S, Kaupp M, Hayton TW.  2013.  A rare uranyl(VI)-alkyl ate complex [Li(DME)1.5]2[UO2(CH2SiMe3)4] and its comparison with a homoleptic uranium(VI)-hexaalkyl. Angew Chem Int Ed Engl. 52(11):3259-63.
Lewis RA, Smiles DE, Darmon JM, S. Stieber CE, Wu G, Hayton TW.  2013.  Reactivity and Mössbauer spectroscopic characterization of an Fe(IV) ketimide complex and reinvestigation of an Fe(IV) norbornyl complex. Inorg Chem. 52(14):8218-27.
Hartmann NJ, Wu G, Hayton TW.  2016.  Reactivity of a Nickel Sulfide with Carbon Monoxide and Nitric Oxide. Journal of the American Chemical Society. 138:12352-12355.
Kent GT, Staun SL, Wu G, Hayton TW.  2020.  Reactivity of [Ce(NR2)3] (R = SiMe3) with Prospective Carbon Atom Transfer Reagents. Organometallics. 39:2375–2382.
Hayton TW, Patrick BO, Legzdins P.  2004.  Reactivity of (trimpsi)V(NO)X2 Complexes (X = Cl, Br, I; trimpsi = tBuSi(CH2PMe2)3). Synthesis of the First Group 5 Alkyl Nitrosyls. Organometallics. 23:657-664.
Smiles DE, Wu G, Hayton TW.  2015.  Reactivity of [U(CH2SiMe2NSiMe3)(NR2)2] (R = SiMe3) with elemental chalcogens: towards a better understanding of chalcogen atom transfer in the actinides. New J Chem. 39:7563-7566.
Schnaars DD, Wu G, Hayton TW.  2008.  Reactivity of UH3 with mild oxidants. Dalton Trans. (44):6121-6.
Schnaars DD, Wu G, Hayton TW.  2009.  Reactivity of UI4(OEt2)2 with phenols: probing the chemistry of the U-I bond. Dalton Trans. (19):3681-7.
Hayton TW.  2013.  Recent developments in actinide-ligand multiple bonding. Chem Commun (Camb). 49(29):2956-73.
Wright AM, Hayton TW.  2012.  Recent Developments in Late Metal Nitrosyl Chemistry. Comments on Inorganic Chemistry. 33:207-248.
Keener M, Hunt C, Carroll TG, Kampel V, Dobrovetsky R, Hayton TW, Ménard G.  2020.  Redox-switchable carboranes for uranium capture and release. Nature. 577:652–655.
Schnaars DD, Wu G, Hayton TW.  2009.  Reduction of pentavalent uranyl to U(IV) facilitated by oxo functionalization. J Am Chem Soc. 131(48):17532-3.
Staun SL, Kent GT, Gomez-Torres A, Wu G, Fortier S, Hayton TW.  2021.  Reductive Coupling of Xylyl Isocyanide Mediated by Low-Valent Uranium. Organometallics. 40:2934–2938.
Pedrick EA, Wu G, Kaltsoyannis N, Hayton TW.  2014.  Reductive silylation of a uranyl dibenzoylmethanate complex: an example of controlled uranyl oxo ligand cleavage. Chem Sci. 5:3204-3213.
Pedrick EA, Wu G, Hayton TW.  2014.  Reductive silylation of the uranyl ion with Ph3SiOTf. Inorg Chem. 53(23):12237-9.
Cook AW, Wu G, Hayton TW.  2018.  A Re-examination of the Synthesis of Monolayer-Protected Cox(SCH2CH2Ph)m Nanoclusters: Unexpected Formation of a Thiolate-Protected Co(II) T3 Supertetrahedron. Inorganic Chemistry. 57(14):8189–8194.
Smiles DE, Wu G, Hayton TW.  2014.  Reversible chalcogen-atom transfer to a terminal uranium sulfide. Inorg Chem. 53(24):12683-5.
Ordoñez O, Kent GT, Schuerlein MA, Wu G, Hayton TW.  2023.  Ring-Opening in the Actinide Cyclopropyl Complexes [Cp3U(2,2-Diphenylcyclopropyl)]n (n = 0, 1). Organometallics. 42:2347–2352.
Kent G, Yu X, Wu G, Autschbach J, Hayton TW.  2022.  Ring-opening of a Thorium Cyclopropenyl Complex Generates a Transient Thorium-bound Carbene. Chem. Commun.. 58:6805-6808.
Keener M, Mattejat M, Zheng S-L, Wu G, Hayton TW, Ménard G.  2022.  Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes. Chem. Sci.. 13:3369-3374.
Schnaars DD, Wu G, Hayton TW.  2011.  Silylation of the uranyl ion using B(C6F5)3-activated Et3SiH. Inorg Chem. 50(19):9642-9.
Hayton TW, Patrick BO, Legzdins P, W. McNeil S.  2004.  The solid-state molecular structure of W(NO)3Cl3 and the nature of its W-NO bonding. Can J Chem. 82:285-292.
Lewis RA, Wu G, Hayton TW.  2011.  Stabilizing high-valent metal ions with a ketimide ligand set: synthesis of Mn(N=CtBu2)4. Inorg Chem. 50(10):4660-8.
Cinco MÁBaeza, Wu G, Telser J, Hayton TW.  2022.  Structural and Spectroscopic Characterization of a Zinc-Bound N-Oxyphthalimide Radical. Inorganic Chemistry. 61:13250–13255.
Wright AM, Wu G, Hayton TW.  2010.  Structural characterization of a copper nitrosyl complex with a {CuNO}10 configuration. J Am Chem Soc. 132(41):14336-7.
Nguyen T-AD, Cook AW, Wu G, Hayton TW.  2017.  Subnanometer-Sized Copper Clusters: A Critical Re-evaluation of the Synthesis and Characterization of Cu8(MPP)4 (HMPP = 2-Mercapto-5-n-propylpyrimidine). Inorganic Chemistry. 56:8390–8396.
Nguyen T-AD, Goldsmith BR, Zaman HT, Wu G, Peters B, Hayton TW.  2015.  Synthesis and characterization of a Cu14 hydride cluster supported by neutral donor ligands. Chem Eur J. 21(14):5341-4.
Cook AW, Hrobárik P, Damon PL, Najera D, Horváth B, Wu G, Hayton TW.  2019.  Synthesis and Characterization of a Linear, Two-Coordinate Pt(II) Ketimide Complex. Inorganic Chemistry. 58:15927-15935.
Lewis RA, Wu G, Hayton TW.  2010.  Synthesis and characterization of an iron(IV) ketimide complex. J Am Chem Soc. 132(37):12814-6.
Cook AW, Jones ZR, Wu G, Teat SJ, Scott SL, Hayton TW.  2019.  Synthesis and Characterization of “Atlas-Sphere” Copper Nanoclusters: New Insights into the Reaction of Cu2+ with Thiols. Inorganic Chemistry. 58:8739-8749.
Lewis RA, Morochnik S, Chapovetsky A, Wu G, Hayton TW.  2012.  Synthesis and characterization of [M2(N=CtBu2)5]- (M=Mn, Fe, Co): metal ketimide complexes with strong metal-metal interactions. Angew Chem Int Ed Engl. 51(51):12772-5.
Staun SL, Smiles DE, Wu G, Hayton TW.  2024.  Synthesis and characterization of the actinide tosylimido complexes [K(18-crown-6)][An(NSO2-p-tolyl)(NR2)3] (An = U, Th; R = SiMe3). Polyhedron. 249:116787.
Fortier S, Wu G, Hayton TW.  2008.  Synthesis and characterization of three homoleptic alkoxides of uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UVtBu)6], and UVI(OtBu)6. Inorg Chem. 47(11):4752-61.
Kent GT, Cook AW, Damon PL, Lewis RA, Wu G, Hayton TW.  2021.  Synthesis and Characterization of Two “Tied-Back” Lithium Ketimides and Isolation of a Ketimide-Bridged [Cr2]6+ Dimer with Strong Antiferromagnetic Coupling. Inorganic Chemistry. 60:4996–5004.
Ordoñez O, Yu X, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis and Characterization of Two Uranyl-Aryl “Ate” Complexes. Chemistry – A European Journal. 27:5885-5889.
Kent GT, Wu G, Hayton TW.  2019.  Synthesis and Crystallographic Characterization of the Tetravalent Actinide-DOTA Complexes [AnIV8-DOTA)(DMSO)] (An = Th, U). Inorganic Chemistry. 58:8253-8256.
Kent G, Yu X, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis and Electronic Structure Analysis of the Actinide Allenylidenes, [(NR2)3An(CCCPh2)]- (An = U, Th; R = SiMe3). Chemical Science. 12:14383-14388.
Hartmann NJ, Wu G., Hayton TW.  2018.  Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N2O reduction. Chem. Sci.. 9(31):6580-6588.
Pedrick EA, Seaman LA, Scott JC, Griego L, Wu G., Hayton TW.  2016.  Synthesis and Reactivity of a U(IV) Dibenzyne Complex. Organometallics. 35:494-502.
Schettini MF, Wu G, Hayton TW.  2012.  Synthesis and reactivity of a uranyl-imidazolyl complex. Chem Commun (Camb). 48(10):1484-6.
Spencer LP, Gdula RL, Hayton TW, Scott BL, Boncella JM.  2008.  Synthesis and reactivity of bis(imido) uranium(VI) cyclopentadienyl complexes. Chem Commun (Camb). (40):4986-8.
Hayton TW, Boncella JM, Scott BL, Batista ER, P. Hay J.  2006.  Synthesis and reactivity of the imido analogues of the uranyl ion. J Am Chem Soc. 128(32):10549-59.
Fortier S, Wu G, Hayton TW.  2009.  Synthesis and redox chemistry of high-valent uranium aryloxides. Inorg Chem. 48(7):3000-11.
Brown JL, Fortier S, Wu G, Kaltsoyannis N, Hayton TW.  2013.  Synthesis and spectroscopic and computational characterization of the chalcogenido-substituted analogues of the uranyl ion, [OUE]2+ (E = S, Se). J Am Chem Soc. 135(14):5352-5.
Assefa MK, Sergentu D-C, Seaman LA, Wu G, Autschbach J, Hayton TW.  2019.  Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li]2[M(N═CtBuPh)6] (M = Ce, Th). Inorganic Chemistry. 58:12654-12661.
Hayton TW, Wu G.  2008.  Synthesis, characterization, and reactivity of a uranyl β-diketiminate complex. J Am Chem Soc. 130(6):2005-14.
Cook AW, Nguyen T-AD, Buratto WR, Wu G, Hayton TW.  2016.  Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)4(OAc)2] and [Cu3H(dppm)3(OAc)2]. Inorg. Chem.. 55:12435-12440.
Hayton TW, P. Daff J, Legzdins P, Rettig SJ, Patrick BO.  2002.  Synthesis, characterization, and solution redox properties of (trimpsi)M(CO)2(NO) complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3]. Inorg Chem. 41(16):4114-26.
Smiles DE, Wu G, Hayton TW.  2016.  Synthesis, Electrochemistry, and Reactivity of the Actinide Trisulfides [K(18-crown-6)][An(η3-S3)(NR2)3] (An = U, Th; R = SiMe3). Inorganic Chemistry. 55:9150-9153.
Fortier S, Brown JL, Kaltsoyannis N, Wu G, Hayton TW.  2012.  Synthesis, molecular and electronic structure of UV(O)[N(SiMe3)2]3. Inorg Chem. 51(3):1625-33.
Lewis RA, George SP, Chapovetsky A, Wu G, Figueroa JS, Hayton TW.  2013.  Synthesis of a cobalt(IV) ketimide with a squashed tetrahedral geometry. Chem Commun (Camb). 49(28):2888-90.
Hartmann NJ, Wu G, Hayton TW.  2015.  Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide. Angew Chem Int Ed Engl. 54(49):14956-9.
Cinco MBaeza, Wu G, Kaltsoyannis N, Hayton T.  2020.  Synthesis of a “Masked” Terminal Zinc Sulfide and its Reactivity with Brønsted and Lewis Acids. Angew. Chem. Int. Ed.. 59:8947-8951.
Hayton TW, Staun S, Lukens W, Wu G.  2021.  Synthesis of a Mixed-valent Heterobimetallic Actinide Nitride and an Analysis of its Bonding. Chemical Science. 12:15519-15527.
Fortier S, Wu G, Hayton TW.  2010.  Synthesis of a nitrido-substituted analogue of the uranyl ion, [N=U=O]+. J Am Chem Soc. 132(20):6888-9.
Fortier S, Walensky JR, Wu G, Hayton TW.  2011.  Synthesis of a phosphorano-stabilized U(IV)-carbene via one-electron oxidation of a U(III)-ylide adduct. J Am Chem Soc. 133(18):6894-7.
Assefa MK, Wu G, Hayton TW.  2017.  Synthesis of a terminal Ce(iv) oxo complex by photolysis of a Ce(iii) nitrate complex. Chem. Sci.. 8:7873-7878.
Touchton AJ, Wu G, Hayton TW.  2021.  Synthesis of Bis(trityl)iron(II) and Formation of the Iron(0)-Stabilized o,o-Isomer of Gomberg’s Dimer. Organometallics. 40:4045–4049.
Hayton TW, Boncella JM, Scott BL, Palmer PD, Batista ER, P. Hay J.  2005.  Synthesis of imido analogs of the uranyl ion. Science. 310(5756):1941-3.
Kent GT, Yu X, Pauly C, Wu G, Autschbach J, Hayton TW.  2021.  Synthesis of Parent Acetylide and Dicarbide Complexes of Thorium and Uranium and an Examination of Their Electronic Structures. Inorganic Chemistry. 60:15413–15420.
Smiles DE, Wu G, Hayton TW.  2014.  Synthesis of terminal monochalcogenide and dichalcogenide complexes of uranium using polychalcogenides, [En]2- (E = Te, n = 2; E = Se, n = 4), as chalcogen atom transfer reagents. Inorg Chem. 53(19):10240-7.
Smiles DE, Wu G, Hayton TW.  2014.  Synthesis of uranium-ligand multiple bonds by cleavage of a trityl protecting group. J Am Chem Soc. 136(1):96-9.
Pedrick EA, Hrobárik P, Seaman LA, Wu G, Hayton TW.  2016.  Synthesis, structure and bonding of hexaphenyl thorium(iv): observation of a non-octahedral structure. Chem Commun (Camb). 52(4):689-92.
Smiles DE, Wu G, Hrobárik P, Hayton TW.  2017.  Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium. Organometallics. 36:4519–4524.
Damon PL, Hayton TW.  2018.  Tetrachlorido(tetramethylethylenediamine)tantalum(IV), TaCl4(TMEDA). Inorg. Synth.. 37:196-198.
Spencer LP, Yang P, Minasian SG, Jilek RE, Batista ER, Boland KS, Boncella JM, Conradson SD, Clark DL, Hayton TW et al..  2013.  Tetrahalide complexes of the [U(NR)2]2+ ion: synthesis, theory, and chlorine K-edge X-ray absorption spectroscopy. J Am Chem Soc. 135(6):2279-90.
Ng SHK, Adams CS, Hayton TW, Legzdins P, Patrick BO.  2003.  Thermal activation of hydrocarbon C-H bonds initiated by a tungsten allyl complex. J Am Chem Soc. 125(49):15210-23.
Smiles DE, Wu G, Kaltsoyannis N, Hayton TW.  2015.  Thorium-ligand multiple bonds via reductive deprotection of a trityl group. Chem Sci. 6:3891-3899.
Hayton TW, W. McNeil S, Patrick BO, Legzdins P.  2003.  Toward binary nitrosyls: distinctly bent Fe-N-O linkages in base-stabilized Fe(NO)3+ complexes. J Am Chem Soc. 125(42):12935-44.
Hartmann NJ, Wu G, Hayton TW.  2017.  Trapping of an NiII Sulfide by a CoI Fulvene Complex. Organometallics. 36(9):1765–1769.
Scepaniak JJ, Wright AM, Lewis RA, Wu G, Hayton TW.  2012.  Tuning the reactivity of TEMPO by coordination to a Lewis acid: isolation and reactivity of MCl31-TEMPO) (M = Fe, Al). J Am Chem Soc. 134(47):19350-3.
Nguyen TH, Yu X, Kent GT, Autschbach J, Hayton TW.  2023.  U-C Bond Insertion, Ring-Opening, and C-H Activation in a Uranium Bis(diisopropylamino)cyclopropenylidene (BAC) Adduct. Organometallics. 42:1005–1012.
Fortier S, Wu G, Hayton TW.  2010.  U(IV) and U(V) azide complexes supported by amide or aryloxide ligands. Dalton Trans. (2):352-4.
Touchton AJ, Wu G, Hayton TW.  2021.  Understanding the Early Stages of Nickel Sulfide Nanocluster Growth: Isolation of Ni3, Ni4, Ni5, and Ni8 Intermediates. Small. 17:2003133.
Hayton TW.  2018.  Understanding the origins of Oyl-U-Oyl bending in the uranyl (UO22+) ion. Dalton Trans.. 47:1003-1009.
Wright AM, Hayton TW.  2015.  Understanding the role of hyponitrite in nitric oxide reduction. Inorg Chem. 54(19):9330-41.
Hayton TW.  2013.  Uranium chemistry: an actinide milestone. Nat Chem. 5(6):451-2.
Pedrick EA, Assefa MK, Wakefield ME, Wu G, Hayton TW.  2017.  Uranyl Coordination by the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene. Inorganic Chemistry. 56(11):6638–6644.
Assefa MK, Wu G, Hayton TW.  2020.  Uranyl oxo silylation promoted by silsesquioxane coordination. Journal of the American Chemical Society. 142:8738–8747.
Staun SL, Sergentu D-C, Wu G, Autschbach J, Hayton TW.  2019.  Use of 15N NMR spectroscopy to probe covalency in a thorium nitride. Chem. Sci.. 10:6431-6436.
Smiles DE, Wu G, Hrobárik P, Hayton TW.  2016.  Use of 77Se and 125Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(En){N(SiMe3)2}3]- (E = Se, Te; n = 1, 2) and Their Oxo-Uranium(VI) Congeners. J Am Chem Soc. 138(3):814-25.
Hayton TW, Humphrey SM, Cossairt BM, Brutchey RL.  2023.  We Need to Talk about New Materials Characterization. Inorganic Chemistry. 62:13165–13167.