Publications
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2023. Dimerization and ring-opening in bis(diisopropylamino)cyclopropenylidene (BAC) mediated by [U(NR2)3(CCPh)] (R = SiMe3). Dalton Transactions. 52:13868-13871.
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2023. Evaluating f-Orbital Participation in the UV═E Multiple Bonds of [U(E)(NR2)3] (E = O, NSiMe3, NAd; R = SiMe3). Inorganic Chemistry. 62:6447-6457.
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2021. Synthesis of Parent Acetylide and Dicarbide Complexes of Thorium and Uranium and an Examination of Their Electronic Structures. Inorganic Chemistry. 60:15413–15420.
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2019. Enantioselective Alkylation of 2-Alkyl Pyridines Controlled by Organolithium Aggregation. Journal of the American Chemical Society. 141:15024-15028.
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2018. Oxidation of the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene upon Ligation to the Uranyl Ion. Inorganic Chemistry. 57(14):8317–8324.
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2018. Promoting oxo functionalization in the uranyl ion by ligation to ketimides. Journal of Organometallic Chemistry. 857:34-37.
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2017. Uranyl Coordination by the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene. Inorganic Chemistry. 56(11):6638–6644.
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2016. Perturbation of the O–U–O Angle in Uranyl by Coordination to a 12-Membered Macrocycle. Inorganic Chemistry. 55:5693-5701.
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2016. Synthesis and Reactivity of a U(IV) Dibenzyne Complex. Organometallics. 35:494-502.
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2016. Synthesis, structure and bonding of hexaphenyl thorium(iv): observation of a non-octahedral structure. Chem Commun (Camb). 52(4):689-92.
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2015. Oxo Ligand Substitution in a Cationic Uranyl Complex: Synergistic Interaction of an Electrophile and a Reductant. Inorg Chem. 54(14):7038-44.
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2015. Synthesis and characterization of a Cu14 hydride cluster supported by neutral donor ligands. Chem Eur J. 21(14):5341-4.
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2014. Oxidation of alcohols and activated alkanes with Lewis acid-activated TEMPO. Inorg Chem. 53(21):11377-87.
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2014. Reductive silylation of a uranyl dibenzoylmethanate complex: an example of controlled uranyl oxo ligand cleavage. Chem Sci. 5:3204-3213.
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2014. Reductive silylation of the uranyl ion with Ph3SiOTf. Inorg Chem. 53(23):12237-9.
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2013. Comparison of the reactivity of 2-Li-C6H4CH2NMe2 with MCl4 (M=Th, U): isolation of a thorium aryl complex or a uranium benzyne complex. Angew Chem Int Ed Engl. 52(40):10589-92.
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2013. Divergent Reactivity of TEMPO with MBr3 (M = B, Al). Eur J Inorg Chem. 2013:3817–3820.
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2006. Tungsten: Organometallic Chemistry. Encyclopedia of Inorganic Chemistry.
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2005. Synthesis of imido analogs of the uranyl ion. Science. 310(5756):1941-3.
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2004. New details concerning the reactions of nitric oxide with vanadium tetrachloride. Inorg Chem. 43(22):7227-33.
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2004. Reactivity of (trimpsi)V(NO)X2 Complexes (X = Cl, Br, I; trimpsi = tBuSi(CH2PMe2)3). Synthesis of the First Group 5 Alkyl Nitrosyls. Organometallics. 23:657-664.
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2004. The solid-state molecular structure of W(NO)3Cl3 and the nature of its W-NO bonding. Can J Chem. 82:285-292.
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2003. Thermal activation of hydrocarbon C-H bonds initiated by a tungsten allyl complex. J Am Chem Soc. 125(49):15210-23.
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2003. Toward binary nitrosyls: distinctly bent Fe-N-O linkages in base-stabilized Fe(NO)3+ complexes. J Am Chem Soc. 125(42):12935-44.
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2002. Differing reactivities of (trimpsi)M(CO)2(NO) complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3] with halogens and halogen sources. Inorg Chem. 41(21):5388-96.
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2002. Synthesis, characterization, and solution redox properties of (trimpsi)M(CO)2(NO) complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3]. Inorg Chem. 41(16):4114-26.