Publications
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2024. A homoleptic Fe(iv) ketimide complex with a low-lying excited state. Chem. Sci.. 15:16559-16566.
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2023. Evaluating f-Orbital Participation in the UV═E Multiple Bonds of [U(E)(NR2)3] (E = O, NSiMe3, NAd; R = SiMe3). Inorganic Chemistry. 62:6447-6457.
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2023. Measuring Metal–Metal Communication in a Series of Ketimide-Bridged [Fe2]6+ Complexes. Inorganic Chemistry. 62:11829–11836.
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2021. Synthesis and Characterization of Two “Tied-Back” Lithium Ketimides and Isolation of a Ketimide-Bridged [Cr2]6+ Dimer with Strong Antiferromagnetic Coupling. Inorganic Chemistry. 60:4996–5004.
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2021. Synthesis of a Mixed-valent Heterobimetallic Actinide Nitride and an Analysis of its Bonding. Chemical Science. 12:15519-15527.
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2020. An Iron Ketimide Single-molecule Magnet [Fe4(N=CPh2)6] with Suppressed Through-barrier Relaxation. Chem. Sci.. 11:4753-4757.
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2017. Lithium Enolates in the Enantioselective Construction of Tetrasubstituted Carbon Centers with Chiral Lithium Amides as Noncovalent Stereodirecting Auxiliaries. Journal of the American Chemical Society. 139:527-533.
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2016. Ligand Exchange-Induced Growth of an Atomically Precise Cu29 Nanocluster from a Smaller Cluster. Chemistry of Materials. 28:8385–8390.
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2015. Quantifying the Electron Donor and Acceptor Abilities of the Ketimide Ligands in M(N═CtBu2)4 (M = V, Nb, Ta). Inorg Chem. 54(20):10081-95.
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2015. Quantifying the Electron Donor and Acceptor Abilities of the Ketimide Ligands in M(N═CtBu2)4 (M = V, Nb, Ta). Inorg Chem. 54(20):10081-95.
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2013. Enediolate–Dilithium Amide Mixed Aggregates in the Enantioselective Alkylation of Arylacetic Acids: Structural Studies and a Stereochemical Model. J Am Chem Soc. 135:16853-16864.
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2013. Enediolate–Dilithium Amide Mixed Aggregates in the Enantioselective Alkylation of Arylacetic Acids: Structural Studies and a Stereochemical Model. J Am Chem Soc. 135:16853-16864.
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2013. Quantifying the σ and π interactions between U(V) f orbitals and halide, alkyl, alkoxide, amide and ketimide ligands. J Am Chem Soc. 135(29):10742-54.
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2013. Reactivity and Mössbauer spectroscopic characterization of an Fe(IV) ketimide complex and reinvestigation of an Fe(IV) norbornyl complex. Inorg Chem. 52(14):8218-27.
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2013. Synthesis of a cobalt(IV) ketimide with a squashed tetrahedral geometry. Chem Commun (Camb). 49(28):2888-90.
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2012. A complete family of terminal uranium chalcogenides, [U(E)(N{SiMe3}2)3]- (E = O, S, Se, Te). J Am Chem Soc. 134(37):15468-75.
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2012. A direct route to bis(imido)uranium(V) halides via metathesis of uranium tetrachloride. J Am Chem Soc. 134(24):9876-8.
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2012. Probing the 5f orbital contribution to the bonding in a U(V) ketimide complex. J Am Chem Soc. 134(10):4931-40.
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2012. Synthesis and characterization of [M2(N=CtBu2)5]- (M=Mn, Fe, Co): metal ketimide complexes with strong metal-metal interactions. Angew Chem Int Ed Engl. 51(51):12772-5.
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2012. Tuning the reactivity of TEMPO by coordination to a Lewis acid: isolation and reactivity of MCl3(η1-TEMPO) (M = Fe, Al). J Am Chem Soc. 134(47):19350-3.
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2011. Facile reduction of a uranyl(VI) β-ketoiminate complex to U(IV) upon oxo silylation. Inorg Chem. 50(11):5105-12.
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2011. Stabilizing high-valent metal ions with a ketimide ligand set: synthesis of Mn(N=CtBu2)4. Inorg Chem. 50(10):4660-8.
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2010. Synthesis and characterization of an iron(IV) ketimide complex. J Am Chem Soc. 132(37):12814-6.
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2006. Tungsten: Organometallic Chemistry. Encyclopedia of Inorganic Chemistry.
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2004. New details concerning the reactions of nitric oxide with vanadium tetrachloride. Inorg Chem. 43(22):7227-33.
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2004. Reactivity of (trimpsi)V(NO)X2 Complexes (X = Cl, Br, I; trimpsi = tBuSi(CH2PMe2)3). Synthesis of the First Group 5 Alkyl Nitrosyls. Organometallics. 23:657-664.
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2004. The solid-state molecular structure of W(NO)3Cl3 and the nature of its W-NO bonding. Can J Chem. 82:285-292.
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2003. Thermal activation of hydrocarbon C-H bonds initiated by a tungsten allyl complex. J Am Chem Soc. 125(49):15210-23.
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2003. Toward binary nitrosyls: distinctly bent Fe-N-O linkages in base-stabilized Fe(NO)3+ complexes. J Am Chem Soc. 125(42):12935-44.
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2002. Coordination and organometallic chemistry of metal-NO complexes. Chem Rev. 102(4):935-92.
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2002. Differing reactivities of (trimpsi)M(CO)2(NO) complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3] with halogens and halogen sources. Inorg Chem. 41(21):5388-96.
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2002. Di-μ-methoxy-bis[(η5-cyclopentadienyl)(nitrosyl-κ-N)(trimethylsilylmethyl)molybdenum(II)]. Acta Crystallogr C. 58(Pt 7):m377-8.
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2002. (η5-cyclopentadienyl)(p-fluorophenoxo)(nitrosyl)(trimethylsilylmethyl)molybdenum(II). Acta Crystallogr C. 58(Pt 2):m68-9.
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2002. Synthesis, characterization, and solution redox properties of (trimpsi)M(CO)2(NO) complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3]. Inorg Chem. 41(16):4114-26.